Intramolecular functionalization of nonactivated carbons by amidylphosphate radicals. Synthesis of 1,4-epimine compounds

Intramolecular functionalization of nonactivated carbons by amidylphosphate radicals. Synthesis of 1,4-epimine compounds

3 pages, 2 schemes.-- Supporting information available: IR, 1H NMR, and mass spectral data for 1a-c, 2a-c, 3, 4, 5a,b, and 6 (5 pages). Ordering information is given on any current masthead page.

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Main Authors: Betancor, Carmen, Concepción, José I., Hernández, Rosendo, Salazar, José A., Suárez, Ernesto
Other Authors: Comisión Asesora de Investigación Científica y Técnica, CAICYT (España)
Format: artículo biblioteca
Language:English
Published: American Chemical Society 1983-11
Online Access:http://hdl.handle.net/10261/17574
http://dx.doi.org/10.13039/501100007272
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spelling dig-ipna-es-10261-175742012-11-21T23:00:00Z Intramolecular functionalization of nonactivated carbons by amidylphosphate radicals. Synthesis of 1,4-epimine compounds Betancor, Carmen Concepción, José I. Hernández, Rosendo Salazar, José A. Suárez, Ernesto Comisión Asesora de Investigación Científica y Técnica, CAICYT (España) Gobierno de Canarias 3 pages, 2 schemes.-- Supporting information available: IR, 1H NMR, and mass spectral data for 1a-c, 2a-c, 3, 4, 5a,b, and 6 (5 pages). Ordering information is given on any current masthead page. Photolysis of the diethyl, diphenyl, and dibenzyl phosphoramidates 1a-c, 3, and 5a in the presence of lead tetraacetate and iodine results in the formation of the corresponding N-dioxyphosphinyl 1,4-epimine compounds 2a-c, 4, and 6, respectively, in excellent yields, thus providing an effective synthetic method for pyrrolidines. Part of this work was supported by the Investigation Programme of the Comisión Asesora de Investigación Científica y Técnica. J.I.C. expresses his gratitude to the Excmo Cabildo Insular de La Palma for a fellowship. 2009-10-09T09:26:56Z 2009-10-09T09:26:56Z 1983-11 artículo http://purl.org/coar/resource_type/c_6501 Journal of Organic Chemistry 48(23): 4430-4432 (1983) 0022-3263 http://hdl.handle.net/10261/17574 10.1021/jo00171a066 http://dx.doi.org/10.13039/501100007272 en http://dx.doi.org/10.1021/jo00171a066 none 2373 bytes 399963 bytes text/plain application/pdf American Chemical Society
institution IPNA ES
collection DSpace
country España
countrycode ES
component Bibliográfico
access En linea
databasecode dig-ipna-es
tag biblioteca
region Europa del Sur
libraryname Biblioteca del IPNA España
language English
description 3 pages, 2 schemes.-- Supporting information available: IR, 1H NMR, and mass spectral data for 1a-c, 2a-c, 3, 4, 5a,b, and 6 (5 pages). Ordering information is given on any current masthead page.
author2 Comisión Asesora de Investigación Científica y Técnica, CAICYT (España)
author_facet Comisión Asesora de Investigación Científica y Técnica, CAICYT (España)
Betancor, Carmen
Concepción, José I.
Hernández, Rosendo
Salazar, José A.
Suárez, Ernesto
format artículo
author Betancor, Carmen
Concepción, José I.
Hernández, Rosendo
Salazar, José A.
Suárez, Ernesto
spellingShingle Betancor, Carmen
Concepción, José I.
Hernández, Rosendo
Salazar, José A.
Suárez, Ernesto
Intramolecular functionalization of nonactivated carbons by amidylphosphate radicals. Synthesis of 1,4-epimine compounds
author_sort Betancor, Carmen
title Intramolecular functionalization of nonactivated carbons by amidylphosphate radicals. Synthesis of 1,4-epimine compounds
title_short Intramolecular functionalization of nonactivated carbons by amidylphosphate radicals. Synthesis of 1,4-epimine compounds
title_full Intramolecular functionalization of nonactivated carbons by amidylphosphate radicals. Synthesis of 1,4-epimine compounds
title_fullStr Intramolecular functionalization of nonactivated carbons by amidylphosphate radicals. Synthesis of 1,4-epimine compounds
title_full_unstemmed Intramolecular functionalization of nonactivated carbons by amidylphosphate radicals. Synthesis of 1,4-epimine compounds
title_sort intramolecular functionalization of nonactivated carbons by amidylphosphate radicals. synthesis of 1,4-epimine compounds
publisher American Chemical Society
publishDate 1983-11
url http://hdl.handle.net/10261/17574
http://dx.doi.org/10.13039/501100007272
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AT hernandezrosendo intramolecularfunctionalizationofnonactivatedcarbonsbyamidylphosphateradicalssynthesisof14epiminecompounds
AT salazarjosea intramolecularfunctionalizationofnonactivatedcarbonsbyamidylphosphateradicalssynthesisof14epiminecompounds
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