Synthesis of dispiroacetals from carbohydrates by intramolecular hydrogen abstractions
4 pages, 1 figure, 4 schemes.
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Elsevier
1996-08-12
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Online Access: | http://hdl.handle.net/10261/17244 http://dx.doi.org/10.13039/501100008737 |
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dig-ipna-es-10261-172442019-11-18T08:26:56Z Synthesis of dispiroacetals from carbohydrates by intramolecular hydrogen abstractions Dorta, Rosa L. Martín, Ángeles Salazar, José A. Suárez, Ernesto Prangé, Thierry Ministerio de Educación y Ciencia (España) Dirección General de Investigación Científica y Técnica, DGICT (España) Gobierno de Canarias 4 pages, 1 figure, 4 schemes. The synthesis of 1,6,8-trioxadispiro[4.1.5.3]pentadecanes 15 and 16 from D-galactopyranose is described. The key steps are two intramolecular hydrogen abstraction reactions promoted by alkoxy radicals. This work was supported by research project no. PB93-0171 of the Dirección General de Investigación Científica y Técnica and Programmes nos. 93/030 and 93/014 of the Dirección General de Universidades e Investigación del Gobierno de Canarias. A. M. thanks the Ministerio de Educación y Ciencia, Spain, for a fellowship. 2009-09-29T07:53:09Z 2009-09-29T07:53:09Z 1996-08-12 artículo http://purl.org/coar/resource_type/c_6501 Tetrahedron Letters 37(33): 6021-6024 (1996) 0040-4039 http://hdl.handle.net/10261/17244 10.1016/0040-4039(96)01265-8 http://dx.doi.org/10.13039/501100008737 en http://dx.doi.org/10.1016/0040-4039(96)01265-8 none 2373 bytes 326815 bytes text/plain application/pdf Elsevier |
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4 pages, 1 figure, 4 schemes. |
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Ministerio de Educación y Ciencia (España) |
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Ministerio de Educación y Ciencia (España) Dorta, Rosa L. Martín, Ángeles Salazar, José A. Suárez, Ernesto Prangé, Thierry |
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author |
Dorta, Rosa L. Martín, Ángeles Salazar, José A. Suárez, Ernesto Prangé, Thierry |
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Dorta, Rosa L. Martín, Ángeles Salazar, José A. Suárez, Ernesto Prangé, Thierry Synthesis of dispiroacetals from carbohydrates by intramolecular hydrogen abstractions |
author_sort |
Dorta, Rosa L. |
title |
Synthesis of dispiroacetals from carbohydrates by intramolecular hydrogen abstractions |
title_short |
Synthesis of dispiroacetals from carbohydrates by intramolecular hydrogen abstractions |
title_full |
Synthesis of dispiroacetals from carbohydrates by intramolecular hydrogen abstractions |
title_fullStr |
Synthesis of dispiroacetals from carbohydrates by intramolecular hydrogen abstractions |
title_full_unstemmed |
Synthesis of dispiroacetals from carbohydrates by intramolecular hydrogen abstractions |
title_sort |
synthesis of dispiroacetals from carbohydrates by intramolecular hydrogen abstractions |
publisher |
Elsevier |
publishDate |
1996-08-12 |
url |
http://hdl.handle.net/10261/17244 http://dx.doi.org/10.13039/501100008737 |
work_keys_str_mv |
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1777669647768748032 |