Caminatal, an aldehyde sesterterpene with a novel carbon skeleton from the Antarctic sponge Suberites caminatus
4 pages, 2 figures, 1 table.-- Printed version published Jul 28, 2003.
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Elsevier
2003-07-04
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Online Access: | http://hdl.handle.net/10261/13281 http://dx.doi.org/10.13039/501100006280 http://dx.doi.org/10.13039/501100003339 |
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dig-ipna-es-10261-132812019-11-13T12:56:32Z Caminatal, an aldehyde sesterterpene with a novel carbon skeleton from the Antarctic sponge Suberites caminatus Díaz-Marrero, Ana R. Brito, Inmaculada Dorta, Enrique Cueto, Mercedes San Martín, Aurelio Darias, José Ministerio de Ciencia y Tecnología (España) Instituto Antártico Chileno Gobierno de Canarias Consejo Superior de Investigaciones Científicas (España) 4 pages, 2 figures, 1 table.-- Printed version published Jul 28, 2003. A new sesterterpene, caminatal 1, containing a bicyclic terpenoid moiety with an aldehyde appendage in combination with an isolated isoprenic aromatic ring leading to a novel carbon skeleton has been obtained from the Antarctic sponge Suberites caminatus. Its structure and relative stereochemistry were established by spectroscopic evidence and biogenetic considerations. The structure and relative stereochemistry of caminatal 1 are described. This work was supported by Ministerio de Ciencia y Tecnología (MCYT), projects: REN2002-10485-E/ ANT and PPQ2002-02494), Instituto Antártico Chileno (INACH), and DGUI (Gobierno de Canarias: PI2002/044). A.R.D.-M. acknowledges an I3P grant from the CSIC and E.D. acknowledges a fellowship (FPI) from the CICYT. 2009-05-28T07:19:19Z 2009-05-28T07:19:19Z 2003-07-04 artículo http://purl.org/coar/resource_type/c_6501 Tetrahedron Letters 44(31): 5939-5942 (2003) 0040-4039 http://hdl.handle.net/10261/13281 10.1016/S0040-4039(03)01426-6 http://dx.doi.org/10.13039/501100006280 http://dx.doi.org/10.13039/501100003339 en http://dx.doi.org/10.1016/S0040-4039(03)01426-6 none 2373 bytes 108323 bytes text/plain application/pdf Elsevier |
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4 pages, 2 figures, 1 table.-- Printed version published Jul 28, 2003. |
author2 |
Ministerio de Ciencia y Tecnología (España) |
author_facet |
Ministerio de Ciencia y Tecnología (España) Díaz-Marrero, Ana R. Brito, Inmaculada Dorta, Enrique Cueto, Mercedes San Martín, Aurelio Darias, José |
format |
artículo |
author |
Díaz-Marrero, Ana R. Brito, Inmaculada Dorta, Enrique Cueto, Mercedes San Martín, Aurelio Darias, José |
spellingShingle |
Díaz-Marrero, Ana R. Brito, Inmaculada Dorta, Enrique Cueto, Mercedes San Martín, Aurelio Darias, José Caminatal, an aldehyde sesterterpene with a novel carbon skeleton from the Antarctic sponge Suberites caminatus |
author_sort |
Díaz-Marrero, Ana R. |
title |
Caminatal, an aldehyde sesterterpene with a novel carbon skeleton from the Antarctic sponge Suberites caminatus |
title_short |
Caminatal, an aldehyde sesterterpene with a novel carbon skeleton from the Antarctic sponge Suberites caminatus |
title_full |
Caminatal, an aldehyde sesterterpene with a novel carbon skeleton from the Antarctic sponge Suberites caminatus |
title_fullStr |
Caminatal, an aldehyde sesterterpene with a novel carbon skeleton from the Antarctic sponge Suberites caminatus |
title_full_unstemmed |
Caminatal, an aldehyde sesterterpene with a novel carbon skeleton from the Antarctic sponge Suberites caminatus |
title_sort |
caminatal, an aldehyde sesterterpene with a novel carbon skeleton from the antarctic sponge suberites caminatus |
publisher |
Elsevier |
publishDate |
2003-07-04 |
url |
http://hdl.handle.net/10261/13281 http://dx.doi.org/10.13039/501100006280 http://dx.doi.org/10.13039/501100003339 |
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