A new procedure for the hydrophobization of cellulose fibre using laccase and a hydrophobic phenolic compound
A new biotechnological procedure using laccase in combination with a hydrophobic phenolic compound (lauryl gallate) for the hydrophobization of cellulose fibres and internal sizing of paper was developed. Cellulose fibres from hardwood kraft pulp were incubated with laccase (Lac), in combination with lauryl gallate (LG). The Lac-LG treatment resulted in the internal sizing of paper, and also in significantly reduced water penetration in the handsheets and wettability of the paper surface. Paper was found not to be effectively rendered hydrophobic by LG alone. SEM images of the fibre network revealed the presence of the sizing agent a product of the reaction between laccase and lauryl gallate. Binding of lauryl gallate to cellulose fibres was suggested by the increase in kappa number of the pulp and further confirmed by IR spectroscopy. © 2012 Elsevier Ltd.
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Elsevier
2012
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Subjects: | Laccase, Lauryl gallate, Internal sizing, Hydrophobization, Cellulose fiber, |
Online Access: | http://hdl.handle.net/20.500.12792/1627 http://hdl.handle.net/10261/291389 |
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dig-inia-es-10261-2913892023-02-20T07:17:39Z A new procedure for the hydrophobization of cellulose fibre using laccase and a hydrophobic phenolic compound García-Ubasart, J. Colom, J. F. Vila, C. Hernández, N. G. Roncero, M. B. Vidal, T. Laccase Lauryl gallate Internal sizing Hydrophobization Cellulose fiber A new biotechnological procedure using laccase in combination with a hydrophobic phenolic compound (lauryl gallate) for the hydrophobization of cellulose fibres and internal sizing of paper was developed. Cellulose fibres from hardwood kraft pulp were incubated with laccase (Lac), in combination with lauryl gallate (LG). The Lac-LG treatment resulted in the internal sizing of paper, and also in significantly reduced water penetration in the handsheets and wettability of the paper surface. Paper was found not to be effectively rendered hydrophobic by LG alone. SEM images of the fibre network revealed the presence of the sizing agent a product of the reaction between laccase and lauryl gallate. Binding of lauryl gallate to cellulose fibres was suggested by the increase in kappa number of the pulp and further confirmed by IR spectroscopy. © 2012 Elsevier Ltd. 2023-02-20T07:17:39Z 2023-02-20T07:17:39Z 2012 artículo Bioresource Technology 112: 341-344 (2012) 0960-8524 http://hdl.handle.net/20.500.12792/1627 http://hdl.handle.net/10261/291389 10.1016/j.biortech.2012.02.075 en none Elsevier |
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Laccase Lauryl gallate Internal sizing Hydrophobization Cellulose fiber Laccase Lauryl gallate Internal sizing Hydrophobization Cellulose fiber |
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Laccase Lauryl gallate Internal sizing Hydrophobization Cellulose fiber Laccase Lauryl gallate Internal sizing Hydrophobization Cellulose fiber García-Ubasart, J. Colom, J. F. Vila, C. Hernández, N. G. Roncero, M. B. Vidal, T. A new procedure for the hydrophobization of cellulose fibre using laccase and a hydrophobic phenolic compound |
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A new biotechnological procedure using laccase in combination with a hydrophobic phenolic compound (lauryl gallate) for the hydrophobization of cellulose fibres and internal sizing of paper was developed. Cellulose fibres from hardwood kraft pulp were incubated with laccase (Lac), in combination with lauryl gallate (LG). The Lac-LG treatment resulted in the internal sizing of paper, and also in significantly reduced water penetration in the handsheets and wettability of the paper surface. Paper was found not to be effectively rendered hydrophobic by LG alone. SEM images of the fibre network revealed the presence of the sizing agent a product of the reaction between laccase and lauryl gallate. Binding of lauryl gallate to cellulose fibres was suggested by the increase in kappa number of the pulp and further confirmed by IR spectroscopy. © 2012 Elsevier Ltd. |
format |
artículo |
topic_facet |
Laccase Lauryl gallate Internal sizing Hydrophobization Cellulose fiber |
author |
García-Ubasart, J. Colom, J. F. Vila, C. Hernández, N. G. Roncero, M. B. Vidal, T. |
author_facet |
García-Ubasart, J. Colom, J. F. Vila, C. Hernández, N. G. Roncero, M. B. Vidal, T. |
author_sort |
García-Ubasart, J. |
title |
A new procedure for the hydrophobization of cellulose fibre using laccase and a hydrophobic phenolic compound |
title_short |
A new procedure for the hydrophobization of cellulose fibre using laccase and a hydrophobic phenolic compound |
title_full |
A new procedure for the hydrophobization of cellulose fibre using laccase and a hydrophobic phenolic compound |
title_fullStr |
A new procedure for the hydrophobization of cellulose fibre using laccase and a hydrophobic phenolic compound |
title_full_unstemmed |
A new procedure for the hydrophobization of cellulose fibre using laccase and a hydrophobic phenolic compound |
title_sort |
new procedure for the hydrophobization of cellulose fibre using laccase and a hydrophobic phenolic compound |
publisher |
Elsevier |
publishDate |
2012 |
url |
http://hdl.handle.net/20.500.12792/1627 http://hdl.handle.net/10261/291389 |
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