Influence of electrode preparation on the electrochemical behaviour of carbon-based supercapacitors
[EN] This work investigates the influence of electrode preparation on the electrochemical behaviour of carbon-based supercapacitors. Studies were performed using the same activated carbon and polymer polyvynilidene fluoride (PVDF) in the same proportions (10 wt.% PVDF). Only the way in which these components were mixed was modified. The procedure for mixing the activated carbon and the polymer has a significant influence on the electrochemical behaviour of the electrode used in a supercapacitor, as this determines the surface area accessible to the electrolyte. The mixing procedure can be selected in order to ensure optimum performance of the electrode. The use of N-methyl-2-pyrrolidone (NMP) in the mixing procedure, the most common method reported in the literature, blocks a significant part of the porosity of the activated carbon, causing a decrease in capacitance. The addition of the polymer using one of the other methods studied reduces the accessible surface area to a lesser extent, although the use of ball milling causes a decrease in the size of the carbon particles which, in turn, increases the electrode resistance.
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Format: | artículo biblioteca |
Language: | English |
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Springer
2007-06
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Subjects: | Electrochemical behaviour, Carbon-based materials, Supercapacitors, Activated carbon, |
Online Access: | http://hdl.handle.net/10261/88778 |
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dig-incar-es-10261-887782018-11-16T07:55:46Z Influence of electrode preparation on the electrochemical behaviour of carbon-based supercapacitors Ruiz Ruiz, Vanesa Blanco Rodríguez, Clara Granda Ferreira, Marcos Menéndez López, Rosa María Santamaría Ramírez, Ricardo Electrochemical behaviour Carbon-based materials Supercapacitors Activated carbon [EN] This work investigates the influence of electrode preparation on the electrochemical behaviour of carbon-based supercapacitors. Studies were performed using the same activated carbon and polymer polyvynilidene fluoride (PVDF) in the same proportions (10 wt.% PVDF). Only the way in which these components were mixed was modified. The procedure for mixing the activated carbon and the polymer has a significant influence on the electrochemical behaviour of the electrode used in a supercapacitor, as this determines the surface area accessible to the electrolyte. The mixing procedure can be selected in order to ensure optimum performance of the electrode. The use of N-methyl-2-pyrrolidone (NMP) in the mixing procedure, the most common method reported in the literature, blocks a significant part of the porosity of the activated carbon, causing a decrease in capacitance. The addition of the polymer using one of the other methods studied reduces the accessible surface area to a lesser extent, although the use of ball milling causes a decrease in the size of the carbon particles which, in turn, increases the electrode resistance. This work was been performed with financial support from MEC (project MAT2004-03480-C02) and FICYT (project IB05-086-C1). V. Ruiz acknowledges a predoctoral research grant from FICYT Peer reviewed 2013-12-18T08:25:37Z 2013-12-18T08:25:37Z 2007-06 artículo http://purl.org/coar/resource_type/c_6501 Journal of Applied Electrochemistry 37(6): 717-721 (2007) 0021-891X http://hdl.handle.net/10261/88778 10.1007/s10800-007-9305-5 en http://link.springer.com/article/10.1007%2Fs10800-007-9305-5 open Springer |
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Electrochemical behaviour Carbon-based materials Supercapacitors Activated carbon Electrochemical behaviour Carbon-based materials Supercapacitors Activated carbon |
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Electrochemical behaviour Carbon-based materials Supercapacitors Activated carbon Electrochemical behaviour Carbon-based materials Supercapacitors Activated carbon Ruiz Ruiz, Vanesa Blanco Rodríguez, Clara Granda Ferreira, Marcos Menéndez López, Rosa María Santamaría Ramírez, Ricardo Influence of electrode preparation on the electrochemical behaviour of carbon-based supercapacitors |
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[EN] This work investigates the influence of electrode preparation on the electrochemical behaviour of carbon-based supercapacitors. Studies were performed using the same activated carbon and polymer polyvynilidene fluoride (PVDF) in the same proportions (10 wt.% PVDF). Only the way in which these components were mixed was modified. The procedure for mixing the activated carbon and the polymer has a significant influence on the electrochemical behaviour of the electrode used in a supercapacitor, as this determines the surface area accessible to the electrolyte. The mixing procedure can be selected in order to ensure optimum performance of the electrode. The use of N-methyl-2-pyrrolidone (NMP) in the mixing procedure, the most common method reported in the literature, blocks a significant part of the porosity of the activated carbon, causing a decrease in capacitance. The addition of the polymer using one of the other methods studied reduces the accessible surface area to a lesser extent, although the use of ball milling causes a decrease in the size of the carbon particles which, in turn, increases the electrode resistance. |
format |
artículo |
topic_facet |
Electrochemical behaviour Carbon-based materials Supercapacitors Activated carbon |
author |
Ruiz Ruiz, Vanesa Blanco Rodríguez, Clara Granda Ferreira, Marcos Menéndez López, Rosa María Santamaría Ramírez, Ricardo |
author_facet |
Ruiz Ruiz, Vanesa Blanco Rodríguez, Clara Granda Ferreira, Marcos Menéndez López, Rosa María Santamaría Ramírez, Ricardo |
author_sort |
Ruiz Ruiz, Vanesa |
title |
Influence of electrode preparation on the electrochemical behaviour of carbon-based supercapacitors |
title_short |
Influence of electrode preparation on the electrochemical behaviour of carbon-based supercapacitors |
title_full |
Influence of electrode preparation on the electrochemical behaviour of carbon-based supercapacitors |
title_fullStr |
Influence of electrode preparation on the electrochemical behaviour of carbon-based supercapacitors |
title_full_unstemmed |
Influence of electrode preparation on the electrochemical behaviour of carbon-based supercapacitors |
title_sort |
influence of electrode preparation on the electrochemical behaviour of carbon-based supercapacitors |
publisher |
Springer |
publishDate |
2007-06 |
url |
http://hdl.handle.net/10261/88778 |
work_keys_str_mv |
AT ruizruizvanesa influenceofelectrodepreparationontheelectrochemicalbehaviourofcarbonbasedsupercapacitors AT blancorodriguezclara influenceofelectrodepreparationontheelectrochemicalbehaviourofcarbonbasedsupercapacitors AT grandaferreiramarcos influenceofelectrodepreparationontheelectrochemicalbehaviourofcarbonbasedsupercapacitors AT menendezlopezrosamaria influenceofelectrodepreparationontheelectrochemicalbehaviourofcarbonbasedsupercapacitors AT santamariaramirezricardo influenceofelectrodepreparationontheelectrochemicalbehaviourofcarbonbasedsupercapacitors |
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1777668912080486400 |