Integrating anaerobic digestion and pyrolysis for treating digestates derived from sewage sludge and fat wastes

The coupling of biological and thermal technologies allows for the complete conversion of wastes into energy and biochar eliminating the problem of sludge disposal. The valorisation of fatty residues as co-substrate in a mesophilic digester of a wastewater treatment plant was studied considering an integrated approach of co-digestion and pyrolysis. Four digested samples obtained from co-digestion of sewage sludge and butcher’s fat waste were studied by thermogravimetric analysis. The activation energy corresponding to the sludge pyrolysis was calculated by a non-isothermal kinetic. Arrhenius activation energy was lower for the pyrolysis of a digested grease sample (92 kJ mol obtained by OFW and 86 kJ mol obtained by Vyazovkin) than for the pyrolysis of sewage sludge and its blends (164–190 kJ mol obtained by OFW and 162–190 kJ mol obtained by Vyazovkin). The analysis of the integrated approach of anaerobic co-digestion and pyrolysis of digestates demonstrated that the addition of 3% (w/v) of fat to the feeding sludge results in a 25% increase in the electricity obtained from biogas (if a combined heat and power unit is considered for biogas valorisation) and increasing the fat content to 15% allows for covering all thermal needs for drying of digestate and more than doubles (2.4 times) the electricity production when the scenario of digestion and pyrolysis is contemplated.

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Main Authors: González-Arias, Judith, Gil Matellanes, María Victoria, Fernández, Ramón Ángel, Martínez, Elia Judith, Fernández, Camino, Papaharalabos, George, Gómez, Xiomar
Other Authors: Ministerio de Economía y Competitividad (España)
Format: artículo biblioteca
Published: Springer Nature 2020
Subjects:Butcher’s fat waste, Thermal analysis, Kinetics, Energy balance, Heat integration, Process efficiency,
Online Access:http://hdl.handle.net/10261/234490
http://dx.doi.org/10.13039/501100003329
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spelling dig-incar-es-10261-2344902021-03-16T03:04:25Z Integrating anaerobic digestion and pyrolysis for treating digestates derived from sewage sludge and fat wastes González-Arias, Judith Gil Matellanes, María Victoria Fernández, Ramón Ángel Martínez, Elia Judith Fernández, Camino Papaharalabos, George Gómez, Xiomar Ministerio de Economía y Competitividad (España) Butcher’s fat waste Thermal analysis Kinetics Energy balance Heat integration Process efficiency The coupling of biological and thermal technologies allows for the complete conversion of wastes into energy and biochar eliminating the problem of sludge disposal. The valorisation of fatty residues as co-substrate in a mesophilic digester of a wastewater treatment plant was studied considering an integrated approach of co-digestion and pyrolysis. Four digested samples obtained from co-digestion of sewage sludge and butcher’s fat waste were studied by thermogravimetric analysis. The activation energy corresponding to the sludge pyrolysis was calculated by a non-isothermal kinetic. Arrhenius activation energy was lower for the pyrolysis of a digested grease sample (92 kJ mol obtained by OFW and 86 kJ mol obtained by Vyazovkin) than for the pyrolysis of sewage sludge and its blends (164–190 kJ mol obtained by OFW and 162–190 kJ mol obtained by Vyazovkin). The analysis of the integrated approach of anaerobic co-digestion and pyrolysis of digestates demonstrated that the addition of 3% (w/v) of fat to the feeding sludge results in a 25% increase in the electricity obtained from biogas (if a combined heat and power unit is considered for biogas valorisation) and increasing the fat content to 15% allows for covering all thermal needs for drying of digestate and more than doubles (2.4 times) the electricity production when the scenario of digestion and pyrolysis is contemplated. This study was funded by the Ministerio de Economía y Competitividad - FEDER (UNLE15-EE-3070). 2021-03-12T09:50:28Z 2021-03-12T09:50:28Z 2020 2021-03-12T09:50:29Z artículo http://purl.org/coar/resource_type/c_6501 doi: 10.1007/s11356-020-09461-1 issn: 1614-7499 Environmental Science and Pollution Research 27 :32603–32614 (2020) http://hdl.handle.net/10261/234490 10.1007/s11356-020-09461-1 http://dx.doi.org/10.13039/501100003329 http://dx.doi.org/10.1007/s11356-020-09461-1 Sí none Springer Nature
institution INCAR ES
collection DSpace
country España
countrycode ES
component Bibliográfico
access En linea
databasecode dig-incar-es
tag biblioteca
region Europa del Sur
libraryname Biblioteca del INCAR España
topic Butcher’s fat waste
Thermal analysis
Kinetics
Energy balance
Heat integration
Process efficiency
Butcher’s fat waste
Thermal analysis
Kinetics
Energy balance
Heat integration
Process efficiency
spellingShingle Butcher’s fat waste
Thermal analysis
Kinetics
Energy balance
Heat integration
Process efficiency
Butcher’s fat waste
Thermal analysis
Kinetics
Energy balance
Heat integration
Process efficiency
González-Arias, Judith
Gil Matellanes, María Victoria
Fernández, Ramón Ángel
Martínez, Elia Judith
Fernández, Camino
Papaharalabos, George
Gómez, Xiomar
Integrating anaerobic digestion and pyrolysis for treating digestates derived from sewage sludge and fat wastes
description The coupling of biological and thermal technologies allows for the complete conversion of wastes into energy and biochar eliminating the problem of sludge disposal. The valorisation of fatty residues as co-substrate in a mesophilic digester of a wastewater treatment plant was studied considering an integrated approach of co-digestion and pyrolysis. Four digested samples obtained from co-digestion of sewage sludge and butcher’s fat waste were studied by thermogravimetric analysis. The activation energy corresponding to the sludge pyrolysis was calculated by a non-isothermal kinetic. Arrhenius activation energy was lower for the pyrolysis of a digested grease sample (92 kJ mol obtained by OFW and 86 kJ mol obtained by Vyazovkin) than for the pyrolysis of sewage sludge and its blends (164–190 kJ mol obtained by OFW and 162–190 kJ mol obtained by Vyazovkin). The analysis of the integrated approach of anaerobic co-digestion and pyrolysis of digestates demonstrated that the addition of 3% (w/v) of fat to the feeding sludge results in a 25% increase in the electricity obtained from biogas (if a combined heat and power unit is considered for biogas valorisation) and increasing the fat content to 15% allows for covering all thermal needs for drying of digestate and more than doubles (2.4 times) the electricity production when the scenario of digestion and pyrolysis is contemplated.
author2 Ministerio de Economía y Competitividad (España)
author_facet Ministerio de Economía y Competitividad (España)
González-Arias, Judith
Gil Matellanes, María Victoria
Fernández, Ramón Ángel
Martínez, Elia Judith
Fernández, Camino
Papaharalabos, George
Gómez, Xiomar
format artículo
topic_facet Butcher’s fat waste
Thermal analysis
Kinetics
Energy balance
Heat integration
Process efficiency
author González-Arias, Judith
Gil Matellanes, María Victoria
Fernández, Ramón Ángel
Martínez, Elia Judith
Fernández, Camino
Papaharalabos, George
Gómez, Xiomar
author_sort González-Arias, Judith
title Integrating anaerobic digestion and pyrolysis for treating digestates derived from sewage sludge and fat wastes
title_short Integrating anaerobic digestion and pyrolysis for treating digestates derived from sewage sludge and fat wastes
title_full Integrating anaerobic digestion and pyrolysis for treating digestates derived from sewage sludge and fat wastes
title_fullStr Integrating anaerobic digestion and pyrolysis for treating digestates derived from sewage sludge and fat wastes
title_full_unstemmed Integrating anaerobic digestion and pyrolysis for treating digestates derived from sewage sludge and fat wastes
title_sort integrating anaerobic digestion and pyrolysis for treating digestates derived from sewage sludge and fat wastes
publisher Springer Nature
publishDate 2020
url http://hdl.handle.net/10261/234490
http://dx.doi.org/10.13039/501100003329
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