Phenol Adsorption and Photo-oxidation on Porous Carbon/Titania Composites
Carbon/titania composites with different loadings were prepared and investigated for phenol adsorption and photo-oxidation from dilute aqueous solutions. The rate of phenol adsorption increased when titanium oxide (P25, Degussa) was immobilized on the carbon support due to the porous features of the resulting C/TiO2 composites. The kinetics of phenol adsorption were very fast for samples containing low titanium oxide contents, whereas titania loadings above 20 wt% presented some operational problems that prevented their application in aqueous solutions. Those C/TiO2 composites which exhibited higher adsorption rates in the absence of illumination also showed a more rapid disappearance of phenol from aqueous solution under UV light, together with the formation of lower amounts of intermediates. Removal efficiencies close to 100% were obtained for C/TiO2 composites containing ca. 10-15 wt% titanium oxide, with preferential oxidation of phenol through the formation of catechol.
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2010-11
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dig-incar-es-10261-1123572018-11-15T12:58:09Z Phenol Adsorption and Photo-oxidation on Porous Carbon/Titania Composites Fernández Velasco, Leticia Parra Soto, José Bernardo Ovín Ania, María Concepción Carbon/titania composites with different loadings were prepared and investigated for phenol adsorption and photo-oxidation from dilute aqueous solutions. The rate of phenol adsorption increased when titanium oxide (P25, Degussa) was immobilized on the carbon support due to the porous features of the resulting C/TiO2 composites. The kinetics of phenol adsorption were very fast for samples containing low titanium oxide contents, whereas titania loadings above 20 wt% presented some operational problems that prevented their application in aqueous solutions. Those C/TiO2 composites which exhibited higher adsorption rates in the absence of illumination also showed a more rapid disappearance of phenol from aqueous solution under UV light, together with the formation of lower amounts of intermediates. Removal efficiencies close to 100% were obtained for C/TiO2 composites containing ca. 10-15 wt% titanium oxide, with preferential oxidation of phenol through the formation of catechol. The authors acknowledge the support of the Spanish MICINN (CTM2008-01956). LFV thanks CSIC for a pre-doctoral fellowship. COA thanks CSIC for financial support (200980I131). Peer reviewed 2015-03-13T12:45:58Z 2015-03-13T12:45:58Z 2010-11 artículo http://purl.org/coar/resource_type/c_6501 Adsorption Science and Technology 28(8/9): 727-738 (2010) 0263-6174 http://hdl.handle.net/10261/112357 10.1260/0263-6174.28.8-9.727 en Publisher's version http://dx.doi.org/ 10.1260/0263-6174.28.8-9.727 Sí open Multi Science Publishing |
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Carbon/titania composites with different loadings were prepared and investigated for phenol adsorption and photo-oxidation from dilute aqueous solutions. The rate of phenol adsorption increased when titanium oxide (P25, Degussa) was immobilized on the carbon support due to the porous features of the resulting C/TiO2 composites. The kinetics of phenol adsorption were very fast for samples containing low titanium oxide contents, whereas titania loadings above 20 wt% presented some operational problems that prevented their application in aqueous solutions. Those C/TiO2 composites which exhibited higher adsorption rates in the absence of illumination also showed a more rapid disappearance of phenol from aqueous solution under UV light, together with the formation of lower amounts of intermediates. Removal efficiencies close to 100% were obtained for C/TiO2 composites containing ca. 10-15 wt% titanium oxide, with preferential oxidation of phenol through the formation of catechol. |
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artículo |
author |
Fernández Velasco, Leticia Parra Soto, José Bernardo Ovín Ania, María Concepción |
spellingShingle |
Fernández Velasco, Leticia Parra Soto, José Bernardo Ovín Ania, María Concepción Phenol Adsorption and Photo-oxidation on Porous Carbon/Titania Composites |
author_facet |
Fernández Velasco, Leticia Parra Soto, José Bernardo Ovín Ania, María Concepción |
author_sort |
Fernández Velasco, Leticia |
title |
Phenol Adsorption and Photo-oxidation on Porous Carbon/Titania Composites |
title_short |
Phenol Adsorption and Photo-oxidation on Porous Carbon/Titania Composites |
title_full |
Phenol Adsorption and Photo-oxidation on Porous Carbon/Titania Composites |
title_fullStr |
Phenol Adsorption and Photo-oxidation on Porous Carbon/Titania Composites |
title_full_unstemmed |
Phenol Adsorption and Photo-oxidation on Porous Carbon/Titania Composites |
title_sort |
phenol adsorption and photo-oxidation on porous carbon/titania composites |
publisher |
Multi Science Publishing |
publishDate |
2010-11 |
url |
http://hdl.handle.net/10261/112357 |
work_keys_str_mv |
AT fernandezvelascoleticia phenoladsorptionandphotooxidationonporouscarbontitaniacomposites AT parrasotojosebernardo phenoladsorptionandphotooxidationonporouscarbontitaniacomposites AT ovinaniamariaconcepcion phenoladsorptionandphotooxidationonporouscarbontitaniacomposites |
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1777668958141284352 |