Occurrence and transport of pesticides and alkylphenols in water samples along the Ebro River Basin

We report the temporal and geographical variations of a set of 30 pesticides (including triazines, organophosphorus and acetanilides) and industrial compounds in surface waters along the Ebro River during the period 2004–2006. Using descriptive statistics we found that the compounds with industrial origin (tributylphosphate, octylphenol and nonylphenol) appeared in over 60% of the samples analyzed and at very high concentrations, while pesticides had a point source origin in the Ebro delta area and overall low-levels, between 0.005 and 2.575 μg L−1. Correlations among pollutants and their distributions were studied using Principal Component Analysis (PCA), a multivariate exploratory data analysis technique which permitted us to discern between agricultural and industrial source contamination. Over a 3 years period a seasonal trend revealed highest concentrations of pesticides over the spring–summer period following pesticide application.

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Bibliographic Details
Main Authors: Navarro-Ortega, Alícia, Lacorte Bruguera, Silvia, Tauler, Romà, Barceló, Damià
Format: artículo biblioteca
Language:English
Published: Elsevier 2010
Subjects:Monitoring, Priority compounds, Water, Principal Component Analysis (PCA),
Online Access:http://hdl.handle.net/10261/45112
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spelling dig-idaea-es-10261-451122012-02-02T23:00:00Z Occurrence and transport of pesticides and alkylphenols in water samples along the Ebro River Basin Navarro-Ortega, Alícia Lacorte Bruguera, Silvia Tauler, Romà Barceló, Damià Monitoring Priority compounds Water Principal Component Analysis (PCA) We report the temporal and geographical variations of a set of 30 pesticides (including triazines, organophosphorus and acetanilides) and industrial compounds in surface waters along the Ebro River during the period 2004–2006. Using descriptive statistics we found that the compounds with industrial origin (tributylphosphate, octylphenol and nonylphenol) appeared in over 60% of the samples analyzed and at very high concentrations, while pesticides had a point source origin in the Ebro delta area and overall low-levels, between 0.005 and 2.575 μg L−1. Correlations among pollutants and their distributions were studied using Principal Component Analysis (PCA), a multivariate exploratory data analysis technique which permitted us to discern between agricultural and industrial source contamination. Over a 3 years period a seasonal trend revealed highest concentrations of pesticides over the spring–summer period following pesticide application. We are indebted to Marta Terrado for performing GIS maps of the sampling area. The authors also thank Dr. Roser Chaler, Dori Fanjul and Alain Hildebrandt for their assistance with GC–MS. This research project was founded by the European Union under the Global Change and Ecosystems (FP6) Water Cycle and Soil Related Aspects (AquaTerra, Project Number 505428 GOCE). Financial support from Spanish Ministry of Education and Science, Project Number CTM2005-25168-E. Alícia Navarro acknowledges the support by a grant of the Departament d’Universitats, Recerca i Societat de la Informació de la Generalitat de Catalunya (2004FI 00856). This work reflects only authors’ views and the European Community is not liable for any use that may be made of the information contained. Peer reviewed 2012-02-03T09:14:41Z 2012-02-03T09:14:41Z 2010 artículo http://purl.org/coar/resource_type/c_6501 Journal of Hydrology 0022-1694 http://hdl.handle.net/10261/45112 10.1016/j.jhydrol.2009.06.039 en http://dx.doi.org/10.1016/j.jhydrol.2009.06.039 none Elsevier
institution IDAEA ES
collection DSpace
country España
countrycode ES
component Bibliográfico
access En linea
databasecode dig-idaea-es
tag biblioteca
region Europa del Sur
libraryname Biblioteca del IDAEA España
language English
topic Monitoring
Priority compounds
Water
Principal Component Analysis (PCA)
Monitoring
Priority compounds
Water
Principal Component Analysis (PCA)
spellingShingle Monitoring
Priority compounds
Water
Principal Component Analysis (PCA)
Monitoring
Priority compounds
Water
Principal Component Analysis (PCA)
Navarro-Ortega, Alícia
Lacorte Bruguera, Silvia
Tauler, Romà
Barceló, Damià
Occurrence and transport of pesticides and alkylphenols in water samples along the Ebro River Basin
description We report the temporal and geographical variations of a set of 30 pesticides (including triazines, organophosphorus and acetanilides) and industrial compounds in surface waters along the Ebro River during the period 2004–2006. Using descriptive statistics we found that the compounds with industrial origin (tributylphosphate, octylphenol and nonylphenol) appeared in over 60% of the samples analyzed and at very high concentrations, while pesticides had a point source origin in the Ebro delta area and overall low-levels, between 0.005 and 2.575 μg L−1. Correlations among pollutants and their distributions were studied using Principal Component Analysis (PCA), a multivariate exploratory data analysis technique which permitted us to discern between agricultural and industrial source contamination. Over a 3 years period a seasonal trend revealed highest concentrations of pesticides over the spring–summer period following pesticide application.
format artículo
topic_facet Monitoring
Priority compounds
Water
Principal Component Analysis (PCA)
author Navarro-Ortega, Alícia
Lacorte Bruguera, Silvia
Tauler, Romà
Barceló, Damià
author_facet Navarro-Ortega, Alícia
Lacorte Bruguera, Silvia
Tauler, Romà
Barceló, Damià
author_sort Navarro-Ortega, Alícia
title Occurrence and transport of pesticides and alkylphenols in water samples along the Ebro River Basin
title_short Occurrence and transport of pesticides and alkylphenols in water samples along the Ebro River Basin
title_full Occurrence and transport of pesticides and alkylphenols in water samples along the Ebro River Basin
title_fullStr Occurrence and transport of pesticides and alkylphenols in water samples along the Ebro River Basin
title_full_unstemmed Occurrence and transport of pesticides and alkylphenols in water samples along the Ebro River Basin
title_sort occurrence and transport of pesticides and alkylphenols in water samples along the ebro river basin
publisher Elsevier
publishDate 2010
url http://hdl.handle.net/10261/45112
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