Effect-Directed Analysis of Key Toxicants in European River Basins. A Review
9 pages, 3 figures, 1 table.
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Language: | English |
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Springer
2007-05-01
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Subjects: | Aquatic ecosystems, Chemical contamination, Ecotoxity, Effect-based key toxicants, Effect-directed analysis (EDA), European river basins, Sediments, Weight-of-evidence, Water Framework Directive (WFD), |
Online Access: | http://hdl.handle.net/10261/11074 |
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dig-idaea-es-10261-110742020-05-25T08:38:02Z Effect-Directed Analysis of Key Toxicants in European River Basins. A Review Brack, Werner Klamer, Hans J. C. López de Alda, Miren Barceló, Damià Aquatic ecosystems Chemical contamination Ecotoxity Effect-based key toxicants Effect-directed analysis (EDA) European river basins Sediments Weight-of-evidence Water Framework Directive (WFD) 9 pages, 3 figures, 1 table. Background. Extensive monitoring programs on chemical contamination are run in many European river basins. With respect to the implementation of the European Union (EU) Water Framework Directive (WFD), these programs are increasingly accompanied by monitoring the ecological status of the river basins. Assuming an impact of chemical contamination on the ecological status, the assignment of effects in aquatic ecosystems to those stressors that cause the effects is a prerequisite for taking political or technical measures to achieve the goals of the WFD. Thus, one focus of present European research is on toxicant identification in European river basins in order to allow for a reduction of toxic pressure on aquatic ecosystems according to the WFD. Main Features. An overview is presented on studies that were performed to link chemical pollution in European river basins to measurable ecotoxic effects. This includes correlation-based approaches as well as investigations that apply effect-directed analysis (EDA) integrating toxicity testing, fractionation and non-target chemical analysis. Effect-based key toxicants that were identified in European surface waters are compiled and compared to EU priority pollutants. Further needs for research are identified. Results. Studies on the identification of effect-based key toxicants focused on mutagenicity, aryl hydrocarbon receptor-mediated effects, endocrine disruption, green algae, and invertebrates. The identified pollutants include priority pollutants and other well-known environmental pollutants such as polycyclic aromatic hydrocarbons, polychlorinated dibenzo-p-dioxins, furans, and biphenyls, nonylphenol, some pesticides and tributyltin, but also other compounds that were neither considered as environmental pollutants before nor regulated such as substituted phenols, natural or synthetic estrogens and androgens, dinaphthofurans, 2-(2-naphthalenyl)benzothiophene, and N-phenyl- 2-naphthylamine. Discussion. Individual studies at specific sites in a European river basin demonstrated the power of combined biological and chemical analytical approaches and, particularly, of effect-directed analysis. However, the available information on effect-based key toxicants is very limited with respect to the entirety of rivers possibly at risk due to chemical contamination and with respect to toxicological endpoints considered at a specific site. A relatively broad basis of information exists only for estrogenicity and aryl hydrocarbon Ah-receptor-mediated effects. We would like to thank all MODELKEY partners for their contribution to the project. We gratefully acknowledge the financial support granted by the European Commission (Contract No 511237-GOCE). Peer reviewed 2009-02-27T11:08:10Z 2009-02-27T11:08:10Z 2007-05-01 artículo http://purl.org/coar/resource_type/c_6501 Environmental Science and Pollution Research 14 (1): 30-38 (2007) 0944-1344 http://hdl.handle.net/10261/11074 10.1065/espr2006.08.329 1614-7499 en http://dx.doi.org/10.1065/espr2006.08.329 none 162 bytes application/msword Springer |
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topic |
Aquatic ecosystems Chemical contamination Ecotoxity Effect-based key toxicants Effect-directed analysis (EDA) European river basins Sediments Weight-of-evidence Water Framework Directive (WFD) Aquatic ecosystems Chemical contamination Ecotoxity Effect-based key toxicants Effect-directed analysis (EDA) European river basins Sediments Weight-of-evidence Water Framework Directive (WFD) |
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Aquatic ecosystems Chemical contamination Ecotoxity Effect-based key toxicants Effect-directed analysis (EDA) European river basins Sediments Weight-of-evidence Water Framework Directive (WFD) Aquatic ecosystems Chemical contamination Ecotoxity Effect-based key toxicants Effect-directed analysis (EDA) European river basins Sediments Weight-of-evidence Water Framework Directive (WFD) Brack, Werner Klamer, Hans J. C. López de Alda, Miren Barceló, Damià Effect-Directed Analysis of Key Toxicants in European River Basins. A Review |
description |
9 pages, 3 figures, 1 table. |
format |
artículo |
topic_facet |
Aquatic ecosystems Chemical contamination Ecotoxity Effect-based key toxicants Effect-directed analysis (EDA) European river basins Sediments Weight-of-evidence Water Framework Directive (WFD) |
author |
Brack, Werner Klamer, Hans J. C. López de Alda, Miren Barceló, Damià |
author_facet |
Brack, Werner Klamer, Hans J. C. López de Alda, Miren Barceló, Damià |
author_sort |
Brack, Werner |
title |
Effect-Directed Analysis of Key Toxicants in European River Basins. A Review |
title_short |
Effect-Directed Analysis of Key Toxicants in European River Basins. A Review |
title_full |
Effect-Directed Analysis of Key Toxicants in European River Basins. A Review |
title_fullStr |
Effect-Directed Analysis of Key Toxicants in European River Basins. A Review |
title_full_unstemmed |
Effect-Directed Analysis of Key Toxicants in European River Basins. A Review |
title_sort |
effect-directed analysis of key toxicants in european river basins. a review |
publisher |
Springer |
publishDate |
2007-05-01 |
url |
http://hdl.handle.net/10261/11074 |
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1777669138680905728 |