Pilot plant scale-up of the production of optimized starch-based biocomposites loaded with cellulosic nanocrystals from Posidonia oceanica waste biomass

Posidonia oceanica biomass has been valorized to produce cellulosic nanocrystals with different purification degrees at lab- and pilot plant-scale. The cellulosic nanocrystals (10 % and 20 % (w/w)) were incorporated into corn starch, producing biocomposite films by melt mixing and hot-pressing at lab-scale. Biocomposite films showed remarkable improvements on the mechanical and water barrier performance (up to 10-fold increase in the elastic modulus and 2-fold decrease in the water permeability). Biocomposite packaging structures were also produced at pilot plant-scale by extrusion and thermoforming. Adjusting the plasticizer formulation and increasing the nanocrystals’ loading up to the maximum enabling good processability (10 % (w/w)) allowed the production of trays with enhanced water barrier and mechanical performance, which, unlike the pure starch, kept their shape upon storage. These results highlight the potential of P. oceanica nanocrystals to improve the performance of starch-based packaging structures and demonstrates the potential of the production process to be industrially applied.

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Main Authors: Benito González, Isaac, Göksen, Gülden, Pérez-Bassart, Zaida, López-Rubio, Amparo, Sánchez, Rafael, Alonso, José M., Gavara, Rafael, Gallur, Miriam, Martínez Sanz, Marta
Other Authors: Generalitat Valenciana
Format: artículo biblioteca
Language:English
Published: Elsevier 2021-08-21
Subjects:Cellulosic nanocrystals, Extrusion, Thermoforming, Pilot plant, Waste biomass, Biopolymers,
Online Access:http://hdl.handle.net/10261/250420
http://dx.doi.org/10.13039/501100004837
http://dx.doi.org/10.13039/501100000780
http://dx.doi.org/10.13039/501100003359
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spelling dig-iata-es-10261-2504202022-12-20T16:50:53Z Pilot plant scale-up of the production of optimized starch-based biocomposites loaded with cellulosic nanocrystals from Posidonia oceanica waste biomass Benito González, Isaac Göksen, Gülden Pérez-Bassart, Zaida López-Rubio, Amparo Sánchez, Rafael Alonso, José M. Gavara, Rafael Gallur, Miriam Martínez Sanz, Marta Generalitat Valenciana Ministerio de Ciencia e Innovación (España) European Commission Cellulosic nanocrystals Extrusion Thermoforming Pilot plant Waste biomass Biopolymers Posidonia oceanica biomass has been valorized to produce cellulosic nanocrystals with different purification degrees at lab- and pilot plant-scale. The cellulosic nanocrystals (10 % and 20 % (w/w)) were incorporated into corn starch, producing biocomposite films by melt mixing and hot-pressing at lab-scale. Biocomposite films showed remarkable improvements on the mechanical and water barrier performance (up to 10-fold increase in the elastic modulus and 2-fold decrease in the water permeability). Biocomposite packaging structures were also produced at pilot plant-scale by extrusion and thermoforming. Adjusting the plasticizer formulation and increasing the nanocrystals’ loading up to the maximum enabling good processability (10 % (w/w)) allowed the production of trays with enhanced water barrier and mechanical performance, which, unlike the pure starch, kept their shape upon storage. These results highlight the potential of P. oceanica nanocrystals to improve the performance of starch-based packaging structures and demonstrates the potential of the production process to be industrially applied. This work was financially supported by the Agencia Valenciana de Innovación (AVI) (INNVAL 10/19/009 project), as a result of the outcomes from the BIOCARB-4-FOOD project granted by the “Agencia Estatal de Investigación” and co-funded by the European Union’s Horizon 2020 research and innovation programme (ERA-Net SUSFOOD2). Peer reviewed 2021-09-17T08:27:50Z 2021-09-17T08:27:50Z 2021-08-21 artículo http://purl.org/coar/resource_type/c_6501 Food Packaging and Shelf Life 30: 100730 (2021) 2214-2894 http://hdl.handle.net/10261/250420 10.1016/j.fpsl.2021.100730 http://dx.doi.org/10.13039/501100004837 http://dx.doi.org/10.13039/501100000780 http://dx.doi.org/10.13039/501100003359 en Postprint https://doi.org/10.1016/j.fpsl.2021.100730 Sí open Elsevier
institution IATA ES
collection DSpace
country España
countrycode ES
component Bibliográfico
access En linea
databasecode dig-iata-es
tag biblioteca
region Europa del Sur
libraryname Biblioteca del IATA España
language English
topic Cellulosic nanocrystals
Extrusion
Thermoforming
Pilot plant
Waste biomass
Biopolymers
Cellulosic nanocrystals
Extrusion
Thermoforming
Pilot plant
Waste biomass
Biopolymers
spellingShingle Cellulosic nanocrystals
Extrusion
Thermoforming
Pilot plant
Waste biomass
Biopolymers
Cellulosic nanocrystals
Extrusion
Thermoforming
Pilot plant
Waste biomass
Biopolymers
Benito González, Isaac
Göksen, Gülden
Pérez-Bassart, Zaida
López-Rubio, Amparo
Sánchez, Rafael
Alonso, José M.
Gavara, Rafael
Gallur, Miriam
Martínez Sanz, Marta
Pilot plant scale-up of the production of optimized starch-based biocomposites loaded with cellulosic nanocrystals from Posidonia oceanica waste biomass
description Posidonia oceanica biomass has been valorized to produce cellulosic nanocrystals with different purification degrees at lab- and pilot plant-scale. The cellulosic nanocrystals (10 % and 20 % (w/w)) were incorporated into corn starch, producing biocomposite films by melt mixing and hot-pressing at lab-scale. Biocomposite films showed remarkable improvements on the mechanical and water barrier performance (up to 10-fold increase in the elastic modulus and 2-fold decrease in the water permeability). Biocomposite packaging structures were also produced at pilot plant-scale by extrusion and thermoforming. Adjusting the plasticizer formulation and increasing the nanocrystals’ loading up to the maximum enabling good processability (10 % (w/w)) allowed the production of trays with enhanced water barrier and mechanical performance, which, unlike the pure starch, kept their shape upon storage. These results highlight the potential of P. oceanica nanocrystals to improve the performance of starch-based packaging structures and demonstrates the potential of the production process to be industrially applied.
author2 Generalitat Valenciana
author_facet Generalitat Valenciana
Benito González, Isaac
Göksen, Gülden
Pérez-Bassart, Zaida
López-Rubio, Amparo
Sánchez, Rafael
Alonso, José M.
Gavara, Rafael
Gallur, Miriam
Martínez Sanz, Marta
format artículo
topic_facet Cellulosic nanocrystals
Extrusion
Thermoforming
Pilot plant
Waste biomass
Biopolymers
author Benito González, Isaac
Göksen, Gülden
Pérez-Bassart, Zaida
López-Rubio, Amparo
Sánchez, Rafael
Alonso, José M.
Gavara, Rafael
Gallur, Miriam
Martínez Sanz, Marta
author_sort Benito González, Isaac
title Pilot plant scale-up of the production of optimized starch-based biocomposites loaded with cellulosic nanocrystals from Posidonia oceanica waste biomass
title_short Pilot plant scale-up of the production of optimized starch-based biocomposites loaded with cellulosic nanocrystals from Posidonia oceanica waste biomass
title_full Pilot plant scale-up of the production of optimized starch-based biocomposites loaded with cellulosic nanocrystals from Posidonia oceanica waste biomass
title_fullStr Pilot plant scale-up of the production of optimized starch-based biocomposites loaded with cellulosic nanocrystals from Posidonia oceanica waste biomass
title_full_unstemmed Pilot plant scale-up of the production of optimized starch-based biocomposites loaded with cellulosic nanocrystals from Posidonia oceanica waste biomass
title_sort pilot plant scale-up of the production of optimized starch-based biocomposites loaded with cellulosic nanocrystals from posidonia oceanica waste biomass
publisher Elsevier
publishDate 2021-08-21
url http://hdl.handle.net/10261/250420
http://dx.doi.org/10.13039/501100004837
http://dx.doi.org/10.13039/501100000780
http://dx.doi.org/10.13039/501100003359
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