Physicochemical Properties of Gels Obtained from Corn Porous Starches with Different Levels of Porosity
Porous starches are attracting much attention owing to their adsorption ability of different compounds. However, only their granular structure have been exploited. The objective of the present research is to analyze the structure and properties of the gels obtained from porous starches having diverse degree of porosity (0–15%). Gels are obtained from corn starches with different degree of porosity and their microstructure, gel rheology, hardness, and syneresis during storage is determine. SEM micrographs revealed honeycomb structures with diverse size and number of holes depending on the porosity of the initial porous starches. In addition, when increasing porosity, gels showed lower viscoelasticity, decreasing G′ and G″ and leading to low elastic gels, with also soft texture. Syneresis of starches is accelerate during the storage of the samples during the first week. However, no significant differences are observe during the second week. Therefore, porous starches with diverse porosity offer an attractive alternative to obtain hydrogels with diverse network matrix.
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Language: | English |
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John Wiley & Sons
2018-09-17
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Subjects: | Gel matrix, Microstructure, Porous starch, Viscoelastic behavior, |
Online Access: | http://hdl.handle.net/10261/180220 http://dx.doi.org/10.13039/501100003329 http://dx.doi.org/10.13039/501100000780 http://dx.doi.org/10.13039/501100003359 |
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dig-iata-es-10261-1802202020-04-07T11:34:05Z Physicochemical Properties of Gels Obtained from Corn Porous Starches with Different Levels of Porosity Benavent Gil, Yaiza Román, Laura Gómez, Manuel Rosell, Cristina M. Ministerio de Economía y Competitividad (España) European Commission Generalitat Valenciana Gel matrix Microstructure Porous starch Viscoelastic behavior Porous starches are attracting much attention owing to their adsorption ability of different compounds. However, only their granular structure have been exploited. The objective of the present research is to analyze the structure and properties of the gels obtained from porous starches having diverse degree of porosity (0–15%). Gels are obtained from corn starches with different degree of porosity and their microstructure, gel rheology, hardness, and syneresis during storage is determine. SEM micrographs revealed honeycomb structures with diverse size and number of holes depending on the porosity of the initial porous starches. In addition, when increasing porosity, gels showed lower viscoelasticity, decreasing G′ and G″ and leading to low elastic gels, with also soft texture. Syneresis of starches is accelerate during the storage of the samples during the first week. However, no significant differences are observe during the second week. Therefore, porous starches with diverse porosity offer an attractive alternative to obtain hydrogels with diverse network matrix. Authors acknowledge the financial support of the Spanish Ministry of Economy and Competitiveness (Project AGL2014‐52928‐C2), the European Regional Development Fund (FEDER) and Generalitat Valenciana (Project Prometeo 2017/189). Y. Benavent‐Gil and Laura Román would like to thank predoctoral fellowship from Spanish Ministry of Economy and Competitiveness and from the University of Valladolid, respectively. Peer reviewed 2019-04-16T12:54:09Z 2019-04-16T12:54:09Z 2018-09-17 artículo http://purl.org/coar/resource_type/c_6501 Starch - Starke 71(3-4):1800171 (2019) 0038-9056 http://hdl.handle.net/10261/180220 10.1002/star.201800171 http://dx.doi.org/10.13039/501100003329 http://dx.doi.org/10.13039/501100000780 http://dx.doi.org/10.13039/501100003359 en #PLACEHOLDER_PARENT_METADATA_VALUE# info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/AGL2014‐52928‐C2 Postprint https://doi.org/10.1002/star.201800171 Sí open John Wiley & Sons |
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Gel matrix Microstructure Porous starch Viscoelastic behavior Gel matrix Microstructure Porous starch Viscoelastic behavior |
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Gel matrix Microstructure Porous starch Viscoelastic behavior Gel matrix Microstructure Porous starch Viscoelastic behavior Benavent Gil, Yaiza Román, Laura Gómez, Manuel Rosell, Cristina M. Physicochemical Properties of Gels Obtained from Corn Porous Starches with Different Levels of Porosity |
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Porous starches are attracting much attention owing to their adsorption ability of different compounds. However, only their granular structure have been exploited. The objective of the present research is to analyze the structure and properties of the gels obtained from porous starches having diverse degree of porosity (0–15%). Gels are obtained from corn starches with different degree of porosity and their microstructure, gel rheology, hardness, and syneresis during storage is determine. SEM micrographs revealed honeycomb structures with diverse size and number of holes depending on the porosity of the initial porous starches. In addition, when increasing porosity, gels showed lower viscoelasticity, decreasing G′ and G″ and leading to low elastic gels, with also soft texture. Syneresis of starches is accelerate during the storage of the samples during the first week. However, no significant differences are observe during the second week. Therefore, porous starches with diverse porosity offer an attractive alternative to obtain hydrogels with diverse network matrix. |
author2 |
Ministerio de Economía y Competitividad (España) |
author_facet |
Ministerio de Economía y Competitividad (España) Benavent Gil, Yaiza Román, Laura Gómez, Manuel Rosell, Cristina M. |
format |
artículo |
topic_facet |
Gel matrix Microstructure Porous starch Viscoelastic behavior |
author |
Benavent Gil, Yaiza Román, Laura Gómez, Manuel Rosell, Cristina M. |
author_sort |
Benavent Gil, Yaiza |
title |
Physicochemical Properties of Gels Obtained from Corn Porous Starches with Different Levels of Porosity |
title_short |
Physicochemical Properties of Gels Obtained from Corn Porous Starches with Different Levels of Porosity |
title_full |
Physicochemical Properties of Gels Obtained from Corn Porous Starches with Different Levels of Porosity |
title_fullStr |
Physicochemical Properties of Gels Obtained from Corn Porous Starches with Different Levels of Porosity |
title_full_unstemmed |
Physicochemical Properties of Gels Obtained from Corn Porous Starches with Different Levels of Porosity |
title_sort |
physicochemical properties of gels obtained from corn porous starches with different levels of porosity |
publisher |
John Wiley & Sons |
publishDate |
2018-09-17 |
url |
http://hdl.handle.net/10261/180220 http://dx.doi.org/10.13039/501100003329 http://dx.doi.org/10.13039/501100000780 http://dx.doi.org/10.13039/501100003359 |
work_keys_str_mv |
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_version_ |
1777670079929909248 |