Synthesis, characterization and free radical scavenging properties of rosmarinic acid fatty esters

The hydrophobation of rosmarinic acid with saturated aliphatic primary alcohols of various chain lengths (methanol to eicosanol) was achieved via an acidcatalyzed esterification in the presence of a highly acidic sulfonic resin. The resulting alkyl rosmarinates were isolated, characterized and their global free radical scavenging activity was determined by the 2,2-diphenyl-1-picrylhydrazyl method in the stationary state. Only the dodecyl ester showed a stronger activity than rosmarinic acid.

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Bibliographic Details
Main Authors: Lecomte, Jérôme, Lopez Giraldo, Luis Javier, Laguerre, Mickaël, Baréa, Bruno, Villeneuve, Pierre
Format: article biblioteca
Language:eng
Subjects:Q53 - Contamination et toxicologie des aliments pour animaux, ester, estérification, acide gras, acide phénolique, alcool, radical libre, antioxydant, extrait d'origine végétale, http://aims.fao.org/aos/agrovoc/c_2671, http://aims.fao.org/aos/agrovoc/c_28361, http://aims.fao.org/aos/agrovoc/c_2818, http://aims.fao.org/aos/agrovoc/c_16197, http://aims.fao.org/aos/agrovoc/c_249, http://aims.fao.org/aos/agrovoc/c_33488, http://aims.fao.org/aos/agrovoc/c_511, http://aims.fao.org/aos/agrovoc/c_8166,
Online Access:http://agritrop.cirad.fr/554962/
http://agritrop.cirad.fr/554962/1/document_554962.pdf
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spelling dig-cirad-fr-5549622024-01-28T18:23:40Z http://agritrop.cirad.fr/554962/ http://agritrop.cirad.fr/554962/ Synthesis, characterization and free radical scavenging properties of rosmarinic acid fatty esters. Lecomte Jérôme, Lopez Giraldo Luis Javier, Laguerre Mickaël, Baréa Bruno, Villeneuve Pierre. 2010. Journal of the American Oil Chemists' Society, 87 (6) : 615-620.https://doi.org/10.1007/s11746-010-1543-8 <https://doi.org/10.1007/s11746-010-1543-8> Synthesis, characterization and free radical scavenging properties of rosmarinic acid fatty esters Lecomte, Jérôme Lopez Giraldo, Luis Javier Laguerre, Mickaël Baréa, Bruno Villeneuve, Pierre eng 2010 Journal of the American Oil Chemists' Society Q53 - Contamination et toxicologie des aliments pour animaux ester estérification acide gras acide phénolique alcool radical libre antioxydant extrait d'origine végétale http://aims.fao.org/aos/agrovoc/c_2671 http://aims.fao.org/aos/agrovoc/c_28361 http://aims.fao.org/aos/agrovoc/c_2818 http://aims.fao.org/aos/agrovoc/c_16197 http://aims.fao.org/aos/agrovoc/c_249 http://aims.fao.org/aos/agrovoc/c_33488 http://aims.fao.org/aos/agrovoc/c_511 http://aims.fao.org/aos/agrovoc/c_8166 The hydrophobation of rosmarinic acid with saturated aliphatic primary alcohols of various chain lengths (methanol to eicosanol) was achieved via an acidcatalyzed esterification in the presence of a highly acidic sulfonic resin. The resulting alkyl rosmarinates were isolated, characterized and their global free radical scavenging activity was determined by the 2,2-diphenyl-1-picrylhydrazyl method in the stationary state. Only the dodecyl ester showed a stronger activity than rosmarinic acid. article info:eu-repo/semantics/article Journal Article info:eu-repo/semantics/publishedVersion http://agritrop.cirad.fr/554962/1/document_554962.pdf application/pdf Cirad license info:eu-repo/semantics/restrictedAccess https://agritrop.cirad.fr/mention_legale.html https://doi.org/10.1007/s11746-010-1543-8 10.1007/s11746-010-1543-8 info:eu-repo/semantics/altIdentifier/doi/10.1007/s11746-010-1543-8 info:eu-repo/semantics/altIdentifier/purl/https://doi.org/10.1007/s11746-010-1543-8
institution CIRAD FR
collection DSpace
country Francia
countrycode FR
component Bibliográfico
access En linea
databasecode dig-cirad-fr
tag biblioteca
region Europa del Oeste
libraryname Biblioteca del CIRAD Francia
language eng
topic Q53 - Contamination et toxicologie des aliments pour animaux
ester
estérification
acide gras
acide phénolique
alcool
radical libre
antioxydant
extrait d'origine végétale
http://aims.fao.org/aos/agrovoc/c_2671
http://aims.fao.org/aos/agrovoc/c_28361
http://aims.fao.org/aos/agrovoc/c_2818
http://aims.fao.org/aos/agrovoc/c_16197
http://aims.fao.org/aos/agrovoc/c_249
http://aims.fao.org/aos/agrovoc/c_33488
http://aims.fao.org/aos/agrovoc/c_511
http://aims.fao.org/aos/agrovoc/c_8166
Q53 - Contamination et toxicologie des aliments pour animaux
ester
estérification
acide gras
acide phénolique
alcool
radical libre
antioxydant
extrait d'origine végétale
http://aims.fao.org/aos/agrovoc/c_2671
http://aims.fao.org/aos/agrovoc/c_28361
http://aims.fao.org/aos/agrovoc/c_2818
http://aims.fao.org/aos/agrovoc/c_16197
http://aims.fao.org/aos/agrovoc/c_249
http://aims.fao.org/aos/agrovoc/c_33488
http://aims.fao.org/aos/agrovoc/c_511
http://aims.fao.org/aos/agrovoc/c_8166
spellingShingle Q53 - Contamination et toxicologie des aliments pour animaux
ester
estérification
acide gras
acide phénolique
alcool
radical libre
antioxydant
extrait d'origine végétale
http://aims.fao.org/aos/agrovoc/c_2671
http://aims.fao.org/aos/agrovoc/c_28361
http://aims.fao.org/aos/agrovoc/c_2818
http://aims.fao.org/aos/agrovoc/c_16197
http://aims.fao.org/aos/agrovoc/c_249
http://aims.fao.org/aos/agrovoc/c_33488
http://aims.fao.org/aos/agrovoc/c_511
http://aims.fao.org/aos/agrovoc/c_8166
Q53 - Contamination et toxicologie des aliments pour animaux
ester
estérification
acide gras
acide phénolique
alcool
radical libre
antioxydant
extrait d'origine végétale
http://aims.fao.org/aos/agrovoc/c_2671
http://aims.fao.org/aos/agrovoc/c_28361
http://aims.fao.org/aos/agrovoc/c_2818
http://aims.fao.org/aos/agrovoc/c_16197
http://aims.fao.org/aos/agrovoc/c_249
http://aims.fao.org/aos/agrovoc/c_33488
http://aims.fao.org/aos/agrovoc/c_511
http://aims.fao.org/aos/agrovoc/c_8166
Lecomte, Jérôme
Lopez Giraldo, Luis Javier
Laguerre, Mickaël
Baréa, Bruno
Villeneuve, Pierre
Synthesis, characterization and free radical scavenging properties of rosmarinic acid fatty esters
description The hydrophobation of rosmarinic acid with saturated aliphatic primary alcohols of various chain lengths (methanol to eicosanol) was achieved via an acidcatalyzed esterification in the presence of a highly acidic sulfonic resin. The resulting alkyl rosmarinates were isolated, characterized and their global free radical scavenging activity was determined by the 2,2-diphenyl-1-picrylhydrazyl method in the stationary state. Only the dodecyl ester showed a stronger activity than rosmarinic acid.
format article
topic_facet Q53 - Contamination et toxicologie des aliments pour animaux
ester
estérification
acide gras
acide phénolique
alcool
radical libre
antioxydant
extrait d'origine végétale
http://aims.fao.org/aos/agrovoc/c_2671
http://aims.fao.org/aos/agrovoc/c_28361
http://aims.fao.org/aos/agrovoc/c_2818
http://aims.fao.org/aos/agrovoc/c_16197
http://aims.fao.org/aos/agrovoc/c_249
http://aims.fao.org/aos/agrovoc/c_33488
http://aims.fao.org/aos/agrovoc/c_511
http://aims.fao.org/aos/agrovoc/c_8166
author Lecomte, Jérôme
Lopez Giraldo, Luis Javier
Laguerre, Mickaël
Baréa, Bruno
Villeneuve, Pierre
author_facet Lecomte, Jérôme
Lopez Giraldo, Luis Javier
Laguerre, Mickaël
Baréa, Bruno
Villeneuve, Pierre
author_sort Lecomte, Jérôme
title Synthesis, characterization and free radical scavenging properties of rosmarinic acid fatty esters
title_short Synthesis, characterization and free radical scavenging properties of rosmarinic acid fatty esters
title_full Synthesis, characterization and free radical scavenging properties of rosmarinic acid fatty esters
title_fullStr Synthesis, characterization and free radical scavenging properties of rosmarinic acid fatty esters
title_full_unstemmed Synthesis, characterization and free radical scavenging properties of rosmarinic acid fatty esters
title_sort synthesis, characterization and free radical scavenging properties of rosmarinic acid fatty esters
url http://agritrop.cirad.fr/554962/
http://agritrop.cirad.fr/554962/1/document_554962.pdf
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AT lopezgiraldoluisjavier synthesischaracterizationandfreeradicalscavengingpropertiesofrosmarinicacidfattyesters
AT laguerremickael synthesischaracterizationandfreeradicalscavengingpropertiesofrosmarinicacidfattyesters
AT bareabruno synthesischaracterizationandfreeradicalscavengingpropertiesofrosmarinicacidfattyesters
AT villeneuvepierre synthesischaracterizationandfreeradicalscavengingpropertiesofrosmarinicacidfattyesters
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