Determination of the basic strength of solid catalysts in water by means of a kinetic tracer
The kinetic analysis of the isomerization of glucose into fructose in the presence of solid basic catalysts, cation-exchanged zeolites and anion-modified hydrotalcites, has been performed in order to evaluate the basicity of those solids in water as the solvent and under working reaction conditions. A standardization curve is established by plotting the logarithms of the rate constants of isomerization of glucose against pH for a series of sodium hydroxide solutions at different dilutions. It was then possible to calculate the corresponding pH value of solid basic catalysts from the measurement of their reaction rate constants and extrapolation on the previously established standardization plot. For 1 g of catalyst in 50 ml of water, pH values of 11 were calculated for NaA, Na- and Cs-exchanged X zeolites, and hydrotalcite in its carbonated form, whereas the pH value of meixnerite, the hydroxide form of the hydrotalcite precursor, was close to 12.4, thus confirming its higher basic properties. Moreover, from the determination of pH values after a 24 h-pre-equilibrium of solid catalysts in water, it was also possible to evaluate the percentage of the cationic species passed into solution which well agrees with the percentage obtained from elemental analyses. © 2006 Elsevier B.V. All rights reserved.
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dig-cirad-fr-5356412023-06-16T08:38:49Z http://agritrop.cirad.fr/535641/ http://agritrop.cirad.fr/535641/ Determination of the basic strength of solid catalysts in water by means of a kinetic tracer. Moreau Claude, Lecomte Jérôme, Roux Alain. 2006. Catalysis Communications, 7 (12) : 941-944.https://doi.org/10.1016/j.catcom.2006.04.001 <https://doi.org/10.1016/j.catcom.2006.04.001> Researchers Determination of the basic strength of solid catalysts in water by means of a kinetic tracer Moreau, Claude Lecomte, Jérôme Roux, Alain eng 2006 Catalysis Communications Q60 - Traitement des produits agricoles non alimentaires The kinetic analysis of the isomerization of glucose into fructose in the presence of solid basic catalysts, cation-exchanged zeolites and anion-modified hydrotalcites, has been performed in order to evaluate the basicity of those solids in water as the solvent and under working reaction conditions. A standardization curve is established by plotting the logarithms of the rate constants of isomerization of glucose against pH for a series of sodium hydroxide solutions at different dilutions. It was then possible to calculate the corresponding pH value of solid basic catalysts from the measurement of their reaction rate constants and extrapolation on the previously established standardization plot. For 1 g of catalyst in 50 ml of water, pH values of 11 were calculated for NaA, Na- and Cs-exchanged X zeolites, and hydrotalcite in its carbonated form, whereas the pH value of meixnerite, the hydroxide form of the hydrotalcite precursor, was close to 12.4, thus confirming its higher basic properties. Moreover, from the determination of pH values after a 24 h-pre-equilibrium of solid catalysts in water, it was also possible to evaluate the percentage of the cationic species passed into solution which well agrees with the percentage obtained from elemental analyses. © 2006 Elsevier B.V. All rights reserved. article info:eu-repo/semantics/article Journal Article info:eu-repo/semantics/publishedVersion http://agritrop.cirad.fr/535641/1/535641.pdf text Cirad license info:eu-repo/semantics/restrictedAccess https://agritrop.cirad.fr/mention_legale.html https://doi.org/10.1016/j.catcom.2006.04.001 10.1016/j.catcom.2006.04.001 http://catalogue-bibliotheques.cirad.fr/cgi-bin/koha/opac-detail.pl?biblionumber=194151 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.catcom.2006.04.001 info:eu-repo/semantics/altIdentifier/purl/https://doi.org/10.1016/j.catcom.2006.04.001 |
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Q60 - Traitement des produits agricoles non alimentaires Q60 - Traitement des produits agricoles non alimentaires Moreau, Claude Lecomte, Jérôme Roux, Alain Determination of the basic strength of solid catalysts in water by means of a kinetic tracer |
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The kinetic analysis of the isomerization of glucose into fructose in the presence of solid basic catalysts, cation-exchanged zeolites and anion-modified hydrotalcites, has been performed in order to evaluate the basicity of those solids in water as the solvent and under working reaction conditions. A standardization curve is established by plotting the logarithms of the rate constants of isomerization of glucose against pH for a series of sodium hydroxide solutions at different dilutions. It was then possible to calculate the corresponding pH value of solid basic catalysts from the measurement of their reaction rate constants and extrapolation on the previously established standardization plot. For 1 g of catalyst in 50 ml of water, pH values of 11 were calculated for NaA, Na- and Cs-exchanged X zeolites, and hydrotalcite in its carbonated form, whereas the pH value of meixnerite, the hydroxide form of the hydrotalcite precursor, was close to 12.4, thus confirming its higher basic properties. Moreover, from the determination of pH values after a 24 h-pre-equilibrium of solid catalysts in water, it was also possible to evaluate the percentage of the cationic species passed into solution which well agrees with the percentage obtained from elemental analyses. © 2006 Elsevier B.V. All rights reserved. |
format |
article |
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Q60 - Traitement des produits agricoles non alimentaires |
author |
Moreau, Claude Lecomte, Jérôme Roux, Alain |
author_facet |
Moreau, Claude Lecomte, Jérôme Roux, Alain |
author_sort |
Moreau, Claude |
title |
Determination of the basic strength of solid catalysts in water by means of a kinetic tracer |
title_short |
Determination of the basic strength of solid catalysts in water by means of a kinetic tracer |
title_full |
Determination of the basic strength of solid catalysts in water by means of a kinetic tracer |
title_fullStr |
Determination of the basic strength of solid catalysts in water by means of a kinetic tracer |
title_full_unstemmed |
Determination of the basic strength of solid catalysts in water by means of a kinetic tracer |
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determination of the basic strength of solid catalysts in water by means of a kinetic tracer |
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http://agritrop.cirad.fr/535641/ http://agritrop.cirad.fr/535641/1/535641.pdf |
work_keys_str_mv |
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1768991668508295168 |