Valorization of cacao pod husk through supercritical fluid extraction of phenolic compounds

Cacao pod husk (CPH) is the main co-product of the chocolate industry. In the present work; a Box-Behnken design was employed to optimize the SC-CO2 for the development of suitable and green process focused on obtaining an extract enriched in phenolic compounds from this by-product, considering temperature, pressure and co-solvent (ethanol) as factors. The response variables selected were yield, total phenolics and total antioxidant capacity (ABTS assay). Extraction pressure and ethanol percentage were the main factors influencing the yield of the target compounds. The extract obtained at the optimum conditions (60 °C, 299 bar and 13.7% of ethanol) presented 0.52% of yield, 12.97 mg GAE/g extract and, 0.213 mmol TE/g extract which were well adjusted to the ones predicted. The findings of this study showed that supercritical fluid extraction could be used as a technique to obtain an extract enriched in phenolic compounds from CPH.

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Bibliographic Details
Main Authors: Valadez-Carmona, Lourdes, Ortiz-Moreno, Alicia, Ceballos-reyes, Guillermo, Mendiola, J. A., Ibáñez, Elena
Other Authors: Consejo Nacional de Ciencia y Tecnología (México)
Format: artículo biblioteca
Language:English
Published: Elsevier 2018
Subjects:Supercritical fluid extraction, Phenolic compounds, Antioxidant activity, Cacao pod husk,
Online Access:http://hdl.handle.net/10261/192723
http://dx.doi.org/10.13039/501100003329
http://dx.doi.org/10.13039/501100003141
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spelling dig-cial-es-10261-1927232019-10-17T01:07:44Z Valorization of cacao pod husk through supercritical fluid extraction of phenolic compounds Valadez-Carmona, Lourdes Ortiz-Moreno, Alicia Ceballos-reyes, Guillermo Mendiola, J. A. Ibáñez, Elena Consejo Nacional de Ciencia y Tecnología (México) CSIC-UAM - Instituto de Investigación en Ciencias de la Alimentación (CIAL) Ministerio de Economía y Competitividad (España) Supercritical fluid extraction Phenolic compounds Antioxidant activity Cacao pod husk Cacao pod husk (CPH) is the main co-product of the chocolate industry. In the present work; a Box-Behnken design was employed to optimize the SC-CO2 for the development of suitable and green process focused on obtaining an extract enriched in phenolic compounds from this by-product, considering temperature, pressure and co-solvent (ethanol) as factors. The response variables selected were yield, total phenolics and total antioxidant capacity (ABTS assay). Extraction pressure and ethanol percentage were the main factors influencing the yield of the target compounds. The extract obtained at the optimum conditions (60 °C, 299 bar and 13.7% of ethanol) presented 0.52% of yield, 12.97 mg GAE/g extract and, 0.213 mmol TE/g extract which were well adjusted to the ones predicted. The findings of this study showed that supercritical fluid extraction could be used as a technique to obtain an extract enriched in phenolic compounds from CPH. The authors are grateful to Consejo Nacional de Ciencia y Tecnología (CONACyT) for the fellowship grant number 254415 and IPN for the financial support to accomplishment of research internship in Instituto de Investigación en Ciencias de la Alimentación (CIAL) (CSIC-UAM). This work was supported by the project AGL2014-53609-0 (Ministerio de Economía y Competitividad, Spain). Peer reviewed 2019-10-16T09:30:40Z 2019-10-16T09:30:40Z 2018 artículo http://purl.org/coar/resource_type/c_6501 Journal of Supercritical Fluids 131: 99-105 (2018) 0896-8446 http://hdl.handle.net/10261/192723 10.1016/j.supflu.2017.09.011 1872-8162 http://dx.doi.org/10.13039/501100003329 http://dx.doi.org/10.13039/501100003141 en #PLACEHOLDER_PARENT_METADATA_VALUE# info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/AGL2014-53609-P https://doi.org/10.1016/j.supflu.2017.09.011 Sí none Elsevier
institution CIAL ES
collection DSpace
country España
countrycode ES
component Bibliográfico
access En linea
databasecode dig-cial-es
tag biblioteca
region Europa del Sur
libraryname Biblioteca del CIAL España
language English
topic Supercritical fluid extraction
Phenolic compounds
Antioxidant activity
Cacao pod husk
Supercritical fluid extraction
Phenolic compounds
Antioxidant activity
Cacao pod husk
spellingShingle Supercritical fluid extraction
Phenolic compounds
Antioxidant activity
Cacao pod husk
Supercritical fluid extraction
Phenolic compounds
Antioxidant activity
Cacao pod husk
Valadez-Carmona, Lourdes
Ortiz-Moreno, Alicia
Ceballos-reyes, Guillermo
Mendiola, J. A.
Ibáñez, Elena
Valorization of cacao pod husk through supercritical fluid extraction of phenolic compounds
description Cacao pod husk (CPH) is the main co-product of the chocolate industry. In the present work; a Box-Behnken design was employed to optimize the SC-CO2 for the development of suitable and green process focused on obtaining an extract enriched in phenolic compounds from this by-product, considering temperature, pressure and co-solvent (ethanol) as factors. The response variables selected were yield, total phenolics and total antioxidant capacity (ABTS assay). Extraction pressure and ethanol percentage were the main factors influencing the yield of the target compounds. The extract obtained at the optimum conditions (60 °C, 299 bar and 13.7% of ethanol) presented 0.52% of yield, 12.97 mg GAE/g extract and, 0.213 mmol TE/g extract which were well adjusted to the ones predicted. The findings of this study showed that supercritical fluid extraction could be used as a technique to obtain an extract enriched in phenolic compounds from CPH.
author2 Consejo Nacional de Ciencia y Tecnología (México)
author_facet Consejo Nacional de Ciencia y Tecnología (México)
Valadez-Carmona, Lourdes
Ortiz-Moreno, Alicia
Ceballos-reyes, Guillermo
Mendiola, J. A.
Ibáñez, Elena
format artículo
topic_facet Supercritical fluid extraction
Phenolic compounds
Antioxidant activity
Cacao pod husk
author Valadez-Carmona, Lourdes
Ortiz-Moreno, Alicia
Ceballos-reyes, Guillermo
Mendiola, J. A.
Ibáñez, Elena
author_sort Valadez-Carmona, Lourdes
title Valorization of cacao pod husk through supercritical fluid extraction of phenolic compounds
title_short Valorization of cacao pod husk through supercritical fluid extraction of phenolic compounds
title_full Valorization of cacao pod husk through supercritical fluid extraction of phenolic compounds
title_fullStr Valorization of cacao pod husk through supercritical fluid extraction of phenolic compounds
title_full_unstemmed Valorization of cacao pod husk through supercritical fluid extraction of phenolic compounds
title_sort valorization of cacao pod husk through supercritical fluid extraction of phenolic compounds
publisher Elsevier
publishDate 2018
url http://hdl.handle.net/10261/192723
http://dx.doi.org/10.13039/501100003329
http://dx.doi.org/10.13039/501100003141
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