Pesticides of modern classes in the water and bottom sediments of Taganrog Bay

The rivers flowing into Taganrog Bay are almost entirely surrounded by agricultural land, where the use of chemical plant protection products is inevitable. This, in turn, leads to the ingress of active ingredients (AI) of pesticides into the water and bottom sediments of the water bodies of fisheries importance. In the water and bottom sediments of Taganrog Bay, the content of 20 active ingredients of the pesticides of modern classes most widely used in agriculture in the region, the half-life of which can exceed six months, has been investigated using high-performance liquid chromatography (HPLC). As stipulated by the State Assignment, the research was being conducted throughout the year in 2014–2016 and in the spring and summer seasons in 2020. As a result of this investigation, such moderately toxic substances as clopyralid, pencycuron and tebuconazole have been identified as the main contributors to the pollution, while in 2014–2016, the main contaminant was low-toxic imidacloprid. In 2020, the total content of pesticide AIs has increased considerably both in terms of concentration and the number of substances found. However, the concentrations of pesticide AIs in the living environment of the hydrobionts in Taganrog Bay turned out to be lower than the established maximum allowable concentrations (MAC) developed for the water bodies of fisheries importance.

Saved in:
Bibliographic Details
Main Authors: Valiullin, V.A., Zinchuk, O.A., Karpushina, Yu.E.
Format: Journal Contribution biblioteca
Language:Russian
Published: 2022
Subjects:Maximum allowable concentrations (MAC), High-performance liquid chromatography (HPLC), Chemical plant protection products, Imidacloprid, Pencycuron, Clopyralid, Высокоэффективная жидкостная хроматография (ВЭЖХ), Предельно допустимые концентрации (ПДК), Клопиралид, Пенцикурон, Имидаклоприд, ASFA_2015::P::Pesticides, ASFA_2015::C::Chromatographic techniques, ASFA_2015::T::Toxicants,
Online Access:http://hdl.handle.net/1834/42524
Tags: Add Tag
No Tags, Be the first to tag this record!
id dig-aquadocs-1834-42524
record_format koha
spelling dig-aquadocs-1834-425242023-03-02T02:09:05Z Pesticides of modern classes in the water and bottom sediments of Taganrog Bay Пестициды современных классов в воде и донных отложениях Таганрогского залива Valiullin, V.A. Zinchuk, O.A. Karpushina, Yu.E. Maximum allowable concentrations (MAC) High-performance liquid chromatography (HPLC) Chemical plant protection products Imidacloprid Pencycuron Clopyralid Высокоэффективная жидкостная хроматография (ВЭЖХ) Предельно допустимые концентрации (ПДК) Клопиралид Пенцикурон Имидаклоприд ASFA_2015::P::Pesticides ASFA_2015::C::Chromatographic techniques ASFA_2015::T::Toxicants The rivers flowing into Taganrog Bay are almost entirely surrounded by agricultural land, where the use of chemical plant protection products is inevitable. This, in turn, leads to the ingress of active ingredients (AI) of pesticides into the water and bottom sediments of the water bodies of fisheries importance. In the water and bottom sediments of Taganrog Bay, the content of 20 active ingredients of the pesticides of modern classes most widely used in agriculture in the region, the half-life of which can exceed six months, has been investigated using high-performance liquid chromatography (HPLC). As stipulated by the State Assignment, the research was being conducted throughout the year in 2014–2016 and in the spring and summer seasons in 2020. As a result of this investigation, such moderately toxic substances as clopyralid, pencycuron and tebuconazole have been identified as the main contributors to the pollution, while in 2014–2016, the main contaminant was low-toxic imidacloprid. In 2020, the total content of pesticide AIs has increased considerably both in terms of concentration and the number of substances found. However, the concentrations of pesticide AIs in the living environment of the hydrobionts in Taganrog Bay turned out to be lower than the established maximum allowable concentrations (MAC) developed for the water bodies of fisheries importance. Реки, впадающие в Таганрогский залив, практически повсеместно находятся в окружении земель сельскохозяйственного назначения, где применение химических средств защиты растений неизбежно. Это в свою очередь приводит к попаданию действующих веществ (ДВ) пестицидов в воду и донные отложения водоемов рыбохозяйственного назначения. В воде и донных отложениях Таганрогского залива методом высокоэффективной жидкостной хроматографии (ВЭЖХ) исследовано содержание 20 наиболее используемых в сельском хозяйстве региона ДВ пестицидов современных классов, период полураспада которых может превышать полгода. Согласно государственному заданию, исследования проводились в 2014–2016 гг. на протяжении всего года, а также в весенний и летний периоды 2020 г. В результате исследования установлено, что в 2020 г. основной вклад в загрязнение внесли такие среднетоксичные вещества, как клопиралид, пенцикурон и тебуконазол, тогда как в 2014–2016 гг. основным загрязнителем являлся малотоксичный имидаклоприд. Общий уровень содержания ДВ пестицидов в 2020 г. значительно возрос как по концентрации, так и по количеству найденных веществ. При этом концентрации ДВ пестицидов в среде обитания гидробионтов Таганрогского залива оказались ниже установленных предельно допустимых концентраций (ПДК), разработанных для водоемов рыбохозяйственного назначения. Published Refereed 2023-03-01T08:57:26Z 2023-03-01T08:57:26Z 2022 Journal Contribution 2618-8147 print 2619-1024 online 10.47921/2619-1024_2022_5_3_7 http://hdl.handle.net/1834/42524 ru https://journal.azniirkh.ru/uploads/files/journal/7_13_maket__080922-1.pdf Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/ pp.7-13 Taganrog Bay Azov Sea Таганрогский залив Азовское море
institution UNESCO
collection DSpace
country Francia
countrycode FR
component Bibliográfico
access En linea
databasecode dig-aquadocs
tag biblioteca
region Europa del Oeste
libraryname Repositorio AQUADOCS
language Russian
topic Maximum allowable concentrations (MAC)
High-performance liquid chromatography (HPLC)
Chemical plant protection products
Imidacloprid
Pencycuron
Clopyralid
Высокоэффективная жидкостная хроматография (ВЭЖХ)
Предельно допустимые концентрации (ПДК)
Клопиралид
Пенцикурон
Имидаклоприд
ASFA_2015::P::Pesticides
ASFA_2015::C::Chromatographic techniques
ASFA_2015::T::Toxicants
Maximum allowable concentrations (MAC)
High-performance liquid chromatography (HPLC)
Chemical plant protection products
Imidacloprid
Pencycuron
Clopyralid
Высокоэффективная жидкостная хроматография (ВЭЖХ)
Предельно допустимые концентрации (ПДК)
Клопиралид
Пенцикурон
Имидаклоприд
ASFA_2015::P::Pesticides
ASFA_2015::C::Chromatographic techniques
ASFA_2015::T::Toxicants
spellingShingle Maximum allowable concentrations (MAC)
High-performance liquid chromatography (HPLC)
Chemical plant protection products
Imidacloprid
Pencycuron
Clopyralid
Высокоэффективная жидкостная хроматография (ВЭЖХ)
Предельно допустимые концентрации (ПДК)
Клопиралид
Пенцикурон
Имидаклоприд
ASFA_2015::P::Pesticides
ASFA_2015::C::Chromatographic techniques
ASFA_2015::T::Toxicants
Maximum allowable concentrations (MAC)
High-performance liquid chromatography (HPLC)
Chemical plant protection products
Imidacloprid
Pencycuron
Clopyralid
Высокоэффективная жидкостная хроматография (ВЭЖХ)
Предельно допустимые концентрации (ПДК)
Клопиралид
Пенцикурон
Имидаклоприд
ASFA_2015::P::Pesticides
ASFA_2015::C::Chromatographic techniques
ASFA_2015::T::Toxicants
Valiullin, V.A.
Zinchuk, O.A.
Karpushina, Yu.E.
Pesticides of modern classes in the water and bottom sediments of Taganrog Bay
description The rivers flowing into Taganrog Bay are almost entirely surrounded by agricultural land, where the use of chemical plant protection products is inevitable. This, in turn, leads to the ingress of active ingredients (AI) of pesticides into the water and bottom sediments of the water bodies of fisheries importance. In the water and bottom sediments of Taganrog Bay, the content of 20 active ingredients of the pesticides of modern classes most widely used in agriculture in the region, the half-life of which can exceed six months, has been investigated using high-performance liquid chromatography (HPLC). As stipulated by the State Assignment, the research was being conducted throughout the year in 2014–2016 and in the spring and summer seasons in 2020. As a result of this investigation, such moderately toxic substances as clopyralid, pencycuron and tebuconazole have been identified as the main contributors to the pollution, while in 2014–2016, the main contaminant was low-toxic imidacloprid. In 2020, the total content of pesticide AIs has increased considerably both in terms of concentration and the number of substances found. However, the concentrations of pesticide AIs in the living environment of the hydrobionts in Taganrog Bay turned out to be lower than the established maximum allowable concentrations (MAC) developed for the water bodies of fisheries importance.
format Journal Contribution
topic_facet Maximum allowable concentrations (MAC)
High-performance liquid chromatography (HPLC)
Chemical plant protection products
Imidacloprid
Pencycuron
Clopyralid
Высокоэффективная жидкостная хроматография (ВЭЖХ)
Предельно допустимые концентрации (ПДК)
Клопиралид
Пенцикурон
Имидаклоприд
ASFA_2015::P::Pesticides
ASFA_2015::C::Chromatographic techniques
ASFA_2015::T::Toxicants
author Valiullin, V.A.
Zinchuk, O.A.
Karpushina, Yu.E.
author_facet Valiullin, V.A.
Zinchuk, O.A.
Karpushina, Yu.E.
author_sort Valiullin, V.A.
title Pesticides of modern classes in the water and bottom sediments of Taganrog Bay
title_short Pesticides of modern classes in the water and bottom sediments of Taganrog Bay
title_full Pesticides of modern classes in the water and bottom sediments of Taganrog Bay
title_fullStr Pesticides of modern classes in the water and bottom sediments of Taganrog Bay
title_full_unstemmed Pesticides of modern classes in the water and bottom sediments of Taganrog Bay
title_sort pesticides of modern classes in the water and bottom sediments of taganrog bay
publishDate 2022
url http://hdl.handle.net/1834/42524
work_keys_str_mv AT valiullinva pesticidesofmodernclassesinthewaterandbottomsedimentsoftaganrogbay
AT zinchukoa pesticidesofmodernclassesinthewaterandbottomsedimentsoftaganrogbay
AT karpushinayue pesticidesofmodernclassesinthewaterandbottomsedimentsoftaganrogbay
AT valiullinva pesticidysovremennyhklassovvvodeidonnyhotloženiâhtaganrogskogozaliva
AT zinchukoa pesticidysovremennyhklassovvvodeidonnyhotloženiâhtaganrogskogozaliva
AT karpushinayue pesticidysovremennyhklassovvvodeidonnyhotloženiâhtaganrogskogozaliva
_version_ 1762937032931278848