Pesticides of modern classes in the water and bottom sediments of Taganrog Bay
The rivers flowing into Taganrog Bay are almost entirely surrounded by agricultural land, where the use of chemical plant protection products is inevitable. This, in turn, leads to the ingress of active ingredients (AI) of pesticides into the water and bottom sediments of the water bodies of fisheries importance. In the water and bottom sediments of Taganrog Bay, the content of 20 active ingredients of the pesticides of modern classes most widely used in agriculture in the region, the half-life of which can exceed six months, has been investigated using high-performance liquid chromatography (HPLC). As stipulated by the State Assignment, the research was being conducted throughout the year in 2014–2016 and in the spring and summer seasons in 2020. As a result of this investigation, such moderately toxic substances as clopyralid, pencycuron and tebuconazole have been identified as the main contributors to the pollution, while in 2014–2016, the main contaminant was low-toxic imidacloprid. In 2020, the total content of pesticide AIs has increased considerably both in terms of concentration and the number of substances found. However, the concentrations of pesticide AIs in the living environment of the hydrobionts in Taganrog Bay turned out to be lower than the established maximum allowable concentrations (MAC) developed for the water bodies of fisheries importance.
Main Authors: | , , |
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Format: | Journal Contribution biblioteca |
Language: | Russian |
Published: |
2022
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Subjects: | Maximum allowable concentrations (MAC), High-performance liquid chromatography (HPLC), Chemical plant protection products, Imidacloprid, Pencycuron, Clopyralid, Высокоэффективная жидкостная хроматография (ВЭЖХ), Предельно допустимые концентрации (ПДК), Клопиралид, Пенцикурон, Имидаклоприд, ASFA_2015::P::Pesticides, ASFA_2015::C::Chromatographic techniques, ASFA_2015::T::Toxicants, |
Online Access: | http://hdl.handle.net/1834/42524 |
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dig-aquadocs-1834-425242023-03-02T02:09:05Z Pesticides of modern classes in the water and bottom sediments of Taganrog Bay Пестициды современных классов в воде и донных отложениях Таганрогского залива Valiullin, V.A. Zinchuk, O.A. Karpushina, Yu.E. Maximum allowable concentrations (MAC) High-performance liquid chromatography (HPLC) Chemical plant protection products Imidacloprid Pencycuron Clopyralid Высокоэффективная жидкостная хроматография (ВЭЖХ) Предельно допустимые концентрации (ПДК) Клопиралид Пенцикурон Имидаклоприд ASFA_2015::P::Pesticides ASFA_2015::C::Chromatographic techniques ASFA_2015::T::Toxicants The rivers flowing into Taganrog Bay are almost entirely surrounded by agricultural land, where the use of chemical plant protection products is inevitable. This, in turn, leads to the ingress of active ingredients (AI) of pesticides into the water and bottom sediments of the water bodies of fisheries importance. In the water and bottom sediments of Taganrog Bay, the content of 20 active ingredients of the pesticides of modern classes most widely used in agriculture in the region, the half-life of which can exceed six months, has been investigated using high-performance liquid chromatography (HPLC). As stipulated by the State Assignment, the research was being conducted throughout the year in 2014–2016 and in the spring and summer seasons in 2020. As a result of this investigation, such moderately toxic substances as clopyralid, pencycuron and tebuconazole have been identified as the main contributors to the pollution, while in 2014–2016, the main contaminant was low-toxic imidacloprid. In 2020, the total content of pesticide AIs has increased considerably both in terms of concentration and the number of substances found. However, the concentrations of pesticide AIs in the living environment of the hydrobionts in Taganrog Bay turned out to be lower than the established maximum allowable concentrations (MAC) developed for the water bodies of fisheries importance. Реки, впадающие в Таганрогский залив, практически повсеместно находятся в окружении земель сельскохозяйственного назначения, где применение химических средств защиты растений неизбежно. Это в свою очередь приводит к попаданию действующих веществ (ДВ) пестицидов в воду и донные отложения водоемов рыбохозяйственного назначения. В воде и донных отложениях Таганрогского залива методом высокоэффективной жидкостной хроматографии (ВЭЖХ) исследовано содержание 20 наиболее используемых в сельском хозяйстве региона ДВ пестицидов современных классов, период полураспада которых может превышать полгода. Согласно государственному заданию, исследования проводились в 2014–2016 гг. на протяжении всего года, а также в весенний и летний периоды 2020 г. В результате исследования установлено, что в 2020 г. основной вклад в загрязнение внесли такие среднетоксичные вещества, как клопиралид, пенцикурон и тебуконазол, тогда как в 2014–2016 гг. основным загрязнителем являлся малотоксичный имидаклоприд. Общий уровень содержания ДВ пестицидов в 2020 г. значительно возрос как по концентрации, так и по количеству найденных веществ. При этом концентрации ДВ пестицидов в среде обитания гидробионтов Таганрогского залива оказались ниже установленных предельно допустимых концентраций (ПДК), разработанных для водоемов рыбохозяйственного назначения. Published Refereed 2023-03-01T08:57:26Z 2023-03-01T08:57:26Z 2022 Journal Contribution 2618-8147 print 2619-1024 online 10.47921/2619-1024_2022_5_3_7 http://hdl.handle.net/1834/42524 ru https://journal.azniirkh.ru/uploads/files/journal/7_13_maket__080922-1.pdf Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/ pp.7-13 Taganrog Bay Azov Sea Таганрогский залив Азовское море |
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Maximum allowable concentrations (MAC) High-performance liquid chromatography (HPLC) Chemical plant protection products Imidacloprid Pencycuron Clopyralid Высокоэффективная жидкостная хроматография (ВЭЖХ) Предельно допустимые концентрации (ПДК) Клопиралид Пенцикурон Имидаклоприд ASFA_2015::P::Pesticides ASFA_2015::C::Chromatographic techniques ASFA_2015::T::Toxicants Maximum allowable concentrations (MAC) High-performance liquid chromatography (HPLC) Chemical plant protection products Imidacloprid Pencycuron Clopyralid Высокоэффективная жидкостная хроматография (ВЭЖХ) Предельно допустимые концентрации (ПДК) Клопиралид Пенцикурон Имидаклоприд ASFA_2015::P::Pesticides ASFA_2015::C::Chromatographic techniques ASFA_2015::T::Toxicants |
spellingShingle |
Maximum allowable concentrations (MAC) High-performance liquid chromatography (HPLC) Chemical plant protection products Imidacloprid Pencycuron Clopyralid Высокоэффективная жидкостная хроматография (ВЭЖХ) Предельно допустимые концентрации (ПДК) Клопиралид Пенцикурон Имидаклоприд ASFA_2015::P::Pesticides ASFA_2015::C::Chromatographic techniques ASFA_2015::T::Toxicants Maximum allowable concentrations (MAC) High-performance liquid chromatography (HPLC) Chemical plant protection products Imidacloprid Pencycuron Clopyralid Высокоэффективная жидкостная хроматография (ВЭЖХ) Предельно допустимые концентрации (ПДК) Клопиралид Пенцикурон Имидаклоприд ASFA_2015::P::Pesticides ASFA_2015::C::Chromatographic techniques ASFA_2015::T::Toxicants Valiullin, V.A. Zinchuk, O.A. Karpushina, Yu.E. Pesticides of modern classes in the water and bottom sediments of Taganrog Bay |
description |
The rivers flowing into Taganrog Bay are almost entirely surrounded by agricultural land, where the use of chemical plant protection products is inevitable. This, in turn, leads to the ingress of active ingredients (AI) of pesticides into the water and bottom sediments of the water bodies of fisheries importance. In the water and bottom sediments of Taganrog Bay, the content of 20 active ingredients of the pesticides of modern classes most widely used in agriculture in the region, the half-life of which can exceed six months, has been investigated using high-performance liquid chromatography (HPLC). As stipulated by the State Assignment, the research was being conducted throughout the year in 2014–2016 and in the spring and summer seasons in 2020. As a result of this investigation, such moderately toxic substances as clopyralid, pencycuron and tebuconazole have been identified as the main contributors to the pollution, while in 2014–2016, the main contaminant was low-toxic imidacloprid. In 2020, the total content of pesticide AIs has increased considerably both in terms of concentration and the number of substances found. However, the concentrations of pesticide AIs in the living environment of the hydrobionts in Taganrog Bay turned out to be lower than the established maximum allowable concentrations (MAC) developed for the water bodies of fisheries importance. |
format |
Journal Contribution |
topic_facet |
Maximum allowable concentrations (MAC) High-performance liquid chromatography (HPLC) Chemical plant protection products Imidacloprid Pencycuron Clopyralid Высокоэффективная жидкостная хроматография (ВЭЖХ) Предельно допустимые концентрации (ПДК) Клопиралид Пенцикурон Имидаклоприд ASFA_2015::P::Pesticides ASFA_2015::C::Chromatographic techniques ASFA_2015::T::Toxicants |
author |
Valiullin, V.A. Zinchuk, O.A. Karpushina, Yu.E. |
author_facet |
Valiullin, V.A. Zinchuk, O.A. Karpushina, Yu.E. |
author_sort |
Valiullin, V.A. |
title |
Pesticides of modern classes in the water and bottom sediments of Taganrog Bay |
title_short |
Pesticides of modern classes in the water and bottom sediments of Taganrog Bay |
title_full |
Pesticides of modern classes in the water and bottom sediments of Taganrog Bay |
title_fullStr |
Pesticides of modern classes in the water and bottom sediments of Taganrog Bay |
title_full_unstemmed |
Pesticides of modern classes in the water and bottom sediments of Taganrog Bay |
title_sort |
pesticides of modern classes in the water and bottom sediments of taganrog bay |
publishDate |
2022 |
url |
http://hdl.handle.net/1834/42524 |
work_keys_str_mv |
AT valiullinva pesticidesofmodernclassesinthewaterandbottomsedimentsoftaganrogbay AT zinchukoa pesticidesofmodernclassesinthewaterandbottomsedimentsoftaganrogbay AT karpushinayue pesticidesofmodernclassesinthewaterandbottomsedimentsoftaganrogbay AT valiullinva pesticidysovremennyhklassovvvodeidonnyhotloženiâhtaganrogskogozaliva AT zinchukoa pesticidysovremennyhklassovvvodeidonnyhotloženiâhtaganrogskogozaliva AT karpushinayue pesticidysovremennyhklassovvvodeidonnyhotloženiâhtaganrogskogozaliva |
_version_ |
1762937032931278848 |