Enhancing Co3O4 nanoparticles: Investigating the impact of nickel doping and high-temperature annealing on NiCo2O4/CoO heterostructures.
Abstract: In this study, we investigated the phase transition of cobalt spinel (Co3O4) nanoparticles into Co3−xNixO4/CoO heterostructures by introducing varying amounts of nickel (x = 0.0–0.16) and subjecting the particles to high annealing temperatures of 1000 ℃. X-ray diffraction (XRD) analysis confirmed the Co3−xNixO4CoO structure for all samples. Transmission electron microscopy (TEM) provided further insights into the phase or heterostructure of the samples after annealing, revealing the arrangement of the two phases. Fourier-transform infrared spectroscopy measurements demonstrated a band shift around 537 cm−1 with increasing Ni content, while ultraviolet-visible (UV-Vis) measurements indicated the energy band (Eg). Significant morphological changes were observed in scanning electron microscope (SEM) measurements at 0.16 Ni, displaying irregular agglomerates. Our findings suggest that introducing Ni into the Co3O4 structure and increasing the annealing temperature to 1000 ℃ can lead to the formation of a heterostructured system. Furthermore, our study’s significance is highlighted by the streamlined synthesis of NiCo2O4/CoO using the sol-gel method followed by calcination. This departure from complex techniques provides an efficient route to acquiring the NiCo2O4/CoO system, a promissory material for advancing supercapacitor research.
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Format: | Artigo de periódico biblioteca |
Language: | Ingles English |
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2023-12-21
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Subjects: | Cobaltite, NiCo2O4, Heterostructure, Annealing temperature, TEM, |
Online Access: | http://www.alice.cnptia.embrapa.br/alice/handle/doc/1160173 |
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dig-alice-doc-11601732024-01-16T10:33:48Z Enhancing Co3O4 nanoparticles: Investigating the impact of nickel doping and high-temperature annealing on NiCo2O4/CoO heterostructures. CARDENAS F., L. J. CHIMENOS, J. M. MORENO A., L. C. PARIS, E. C. JOYA, M. R. Facultad de Ingeniería-Departamento de Ingeniería Mecánica y Mecatrónica, Universidad Nacional de Colombia; Departamento de Ciencia de Materiales y Química Física, Universitat de Barcelona, Barcelona, Spain; Laboratorio de aplicaciones fisicoquímicas del estado sólido AFES, Departamento de Química, Universidad Nacional de Colombia-sede Bogotá; ELAINE CRISTINA PARIS, CNPDIA; Departamento de Física, Facultad de Ciencias, Universidad Nacional de Colombia-Bogotá. Cobaltite NiCo2O4 Heterostructure Annealing temperature TEM Abstract: In this study, we investigated the phase transition of cobalt spinel (Co3O4) nanoparticles into Co3−xNixO4/CoO heterostructures by introducing varying amounts of nickel (x = 0.0–0.16) and subjecting the particles to high annealing temperatures of 1000 ℃. X-ray diffraction (XRD) analysis confirmed the Co3−xNixO4CoO structure for all samples. Transmission electron microscopy (TEM) provided further insights into the phase or heterostructure of the samples after annealing, revealing the arrangement of the two phases. Fourier-transform infrared spectroscopy measurements demonstrated a band shift around 537 cm−1 with increasing Ni content, while ultraviolet-visible (UV-Vis) measurements indicated the energy band (Eg). Significant morphological changes were observed in scanning electron microscope (SEM) measurements at 0.16 Ni, displaying irregular agglomerates. Our findings suggest that introducing Ni into the Co3O4 structure and increasing the annealing temperature to 1000 ℃ can lead to the formation of a heterostructured system. Furthermore, our study’s significance is highlighted by the streamlined synthesis of NiCo2O4/CoO using the sol-gel method followed by calcination. This departure from complex techniques provides an efficient route to acquiring the NiCo2O4/CoO system, a promissory material for advancing supercapacitor research. 2024-01-16T10:33:48Z 2024-01-16T10:33:48Z 2023-12-21 2023 Artigo de periódico AIMS Materials Science, v. 10, n. 6, 2023. http://www.alice.cnptia.embrapa.br/alice/handle/doc/1160173 10.3934/matersci.2023058 Ingles en openAccess 1090 - 1104 |
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Cobaltite NiCo2O4 Heterostructure Annealing temperature TEM Cobaltite NiCo2O4 Heterostructure Annealing temperature TEM |
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Cobaltite NiCo2O4 Heterostructure Annealing temperature TEM Cobaltite NiCo2O4 Heterostructure Annealing temperature TEM CARDENAS F., L. J. CHIMENOS, J. M. MORENO A., L. C. PARIS, E. C. JOYA, M. R. Enhancing Co3O4 nanoparticles: Investigating the impact of nickel doping and high-temperature annealing on NiCo2O4/CoO heterostructures. |
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Abstract: In this study, we investigated the phase transition of cobalt spinel (Co3O4) nanoparticles into Co3−xNixO4/CoO heterostructures by introducing varying amounts of nickel (x = 0.0–0.16) and subjecting the particles to high annealing temperatures of 1000 ℃. X-ray diffraction (XRD) analysis confirmed the Co3−xNixO4CoO structure for all samples. Transmission electron microscopy (TEM) provided further insights into the phase or heterostructure of the samples after annealing, revealing the arrangement of the two phases. Fourier-transform infrared spectroscopy measurements demonstrated a band shift around 537 cm−1 with increasing Ni content, while ultraviolet-visible (UV-Vis) measurements indicated the energy band (Eg). Significant morphological changes were observed in scanning electron microscope (SEM) measurements at 0.16 Ni, displaying irregular agglomerates. Our findings suggest that introducing Ni into the Co3O4 structure and increasing the annealing temperature to 1000 ℃ can lead to the formation of a heterostructured system. Furthermore, our study’s significance is highlighted by the streamlined synthesis of NiCo2O4/CoO using the sol-gel method followed by calcination. This departure from complex techniques provides an efficient route to acquiring the NiCo2O4/CoO system, a promissory material for advancing supercapacitor research. |
author2 |
Facultad de Ingeniería-Departamento de Ingeniería Mecánica y Mecatrónica, Universidad Nacional de Colombia; Departamento de Ciencia de Materiales y Química Física, Universitat de Barcelona, Barcelona, Spain; Laboratorio de aplicaciones fisicoquímicas del estado sólido AFES, Departamento de Química, Universidad Nacional de Colombia-sede Bogotá; ELAINE CRISTINA PARIS, CNPDIA; Departamento de Física, Facultad de Ciencias, Universidad Nacional de Colombia-Bogotá. |
author_facet |
Facultad de Ingeniería-Departamento de Ingeniería Mecánica y Mecatrónica, Universidad Nacional de Colombia; Departamento de Ciencia de Materiales y Química Física, Universitat de Barcelona, Barcelona, Spain; Laboratorio de aplicaciones fisicoquímicas del estado sólido AFES, Departamento de Química, Universidad Nacional de Colombia-sede Bogotá; ELAINE CRISTINA PARIS, CNPDIA; Departamento de Física, Facultad de Ciencias, Universidad Nacional de Colombia-Bogotá. CARDENAS F., L. J. CHIMENOS, J. M. MORENO A., L. C. PARIS, E. C. JOYA, M. R. |
format |
Artigo de periódico |
topic_facet |
Cobaltite NiCo2O4 Heterostructure Annealing temperature TEM |
author |
CARDENAS F., L. J. CHIMENOS, J. M. MORENO A., L. C. PARIS, E. C. JOYA, M. R. |
author_sort |
CARDENAS F., L. J. |
title |
Enhancing Co3O4 nanoparticles: Investigating the impact of nickel doping and high-temperature annealing on NiCo2O4/CoO heterostructures. |
title_short |
Enhancing Co3O4 nanoparticles: Investigating the impact of nickel doping and high-temperature annealing on NiCo2O4/CoO heterostructures. |
title_full |
Enhancing Co3O4 nanoparticles: Investigating the impact of nickel doping and high-temperature annealing on NiCo2O4/CoO heterostructures. |
title_fullStr |
Enhancing Co3O4 nanoparticles: Investigating the impact of nickel doping and high-temperature annealing on NiCo2O4/CoO heterostructures. |
title_full_unstemmed |
Enhancing Co3O4 nanoparticles: Investigating the impact of nickel doping and high-temperature annealing on NiCo2O4/CoO heterostructures. |
title_sort |
enhancing co3o4 nanoparticles: investigating the impact of nickel doping and high-temperature annealing on nico2o4/coo heterostructures. |
publishDate |
2023-12-21 |
url |
http://www.alice.cnptia.embrapa.br/alice/handle/doc/1160173 |
work_keys_str_mv |
AT cardenasflj enhancingco3o4nanoparticlesinvestigatingtheimpactofnickeldopingandhightemperatureannealingonnico2o4cooheterostructures AT chimenosjm enhancingco3o4nanoparticlesinvestigatingtheimpactofnickeldopingandhightemperatureannealingonnico2o4cooheterostructures AT morenoalc enhancingco3o4nanoparticlesinvestigatingtheimpactofnickeldopingandhightemperatureannealingonnico2o4cooheterostructures AT parisec enhancingco3o4nanoparticlesinvestigatingtheimpactofnickeldopingandhightemperatureannealingonnico2o4cooheterostructures AT joyamr enhancingco3o4nanoparticlesinvestigatingtheimpactofnickeldopingandhightemperatureannealingonnico2o4cooheterostructures |
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