Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations [electronic resource] /
The present volume is a description of the current knowledge on the different metal-oxo and metal-peroxo species which are involved in catalytic oxidations. These highly reactivity metal-oxygen species are the key intermediates in heme or non-heme oxygenases, as well as in metal-catalyzed oxidations. The accumulated knowledge on these reactive entities will facilitate a better understanding of the different intermediates involved in the catalytic cycles of enzymes like cytochromes P-450, non-heme oxygenases, copper oxygenases, in the oxidation of water by the manganese-center of Photosystem II, in the chemistry of dioxiranes and also in DNA cleavage performed by activated bleomycin. The description of these metal-oxo and metal-peroxo species is based on physico-chemical data, reactivity results and also on theoretical calculations.
Main Authors: | Meunier, Bernard. editor., SpringerLink (Online service) |
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Format: | Texto biblioteca |
Language: | eng |
Published: |
Berlin, Heidelberg : Springer Berlin Heidelberg,
2000
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Subjects: | Chemistry., Inorganic chemistry., Physical chemistry., Chemistry, Physical and theoretical., Catalysis., Biochemistry., Theoretical and Computational Chemistry., Inorganic Chemistry., Biochemistry, general., Physical Chemistry., |
Online Access: | http://dx.doi.org/10.1007/3-540-46592-8 |
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