The Separation of Enantiomers by Capillary Electrophoresis [electronic resource] /

Supplement Vol. 54, 2001 -- 1 Enantiomers and Separation -- 1.1 Introduction -- 1.2 Enantiomers and Living Organisms -- 1.3 The Separation of Enantiomers -- 1.4 Electrophoretic Separation of Enantiomers -- 1.5 Enantiomer Separations by Capillary Electrophoresis -- 1.6 Conclusion -- 2 The Principles of Separation in CE -- 2.1 Introduction: Movement and Separation -- 2.2 Separative and Non-Separative Transport in CE -- 2.3 Electrophoretic Mobility -- 2.4 Electroosmotic Mobility -- 2.5 CE Instrumentation -- 2.6 Conclusion -- 3 Modelling Enantiomer Separation by CE -- 3.1 The Use of Models -- 3.2 Background -- 3.3 The Physical Model -- 3.4 A Basic Mathematical Model -- 3.5 Extended Theoretical Models -- 3.6 Conclusion -- 4 Method Development Strategies -- 4.1 The Purpose of the Method -- 4.2 Factors Controlling Resolution -- 4.3 The Structure of the Analyte -- 4.4 The Choice of Chiral Selector -- 4.5 Other Separation Conditions -- 4.6 Optimisation Approaches -- 4.7 Validation -- 4.8 Computer Simulations -- 4.9 Conclusion -- 5 The Use of Cyclodextrins as Chiral Selectors -- 5.1 Introduction -- 5.2 Structure and Properties -- 5.3 Cyclodextrin Production -- 5.4 Complexation Mechanisms -- 5.5 Cyclodextrin Classes -- 5.6 Analyte Classes -- 5.7 Analyte Structure -- 5.8 Batch and Source Variation -- 5.9 Conclusion -- 6 Other Chiral Selectors -- 6.1 Introduction -- 6.2 Ligand Exchange Selectors -- 6.3 Chiral Surfactants -- 6.4 Alkaloids -- 6.5 Crown Ethers -- 6.6 Natural Macromolecules -- 6.7 Non-Aqueous CE -- 6.8 Derivatisation -- 6.9 Capillary Electrochromatography -- 6.10 Conclusion.