The Role of Rydberg States in Spectroscopy and Photochemistry [electronic resource] : Low and High Rydberg States /
The aim of this volume is to offer a balanced overview of molecular Rydberg spectroscopy as it has developed over recent decades. Recent evolution has split Rydberg spectroscopy into two apparently distinct fields: the one concerns the low (n=3-5) Rydberg states, the other the very high (typically n>150) Rydberg states. The former is aimed at spectral levels where Rydberg, valence-shell, and intermediate-type states interact, with a variety of photochemical consequences. The latter considers states extremely close to the ionization limit, from whereionization is possible with a very slight amount of additional energy. Recently developed techniques make it possible to produce ions in well-defined electronic, vibrational and rotational states, including states resulting from spin-orbit or Jahn-Teller splitting. It is then possible to study the structure and reactions of such state-selected ions as well as those of the corresponding neutral molecules. These techniques amount to badly needed high resolution photoelectron spectroscopy.
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Language: | eng |
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Dordrecht : Springer Netherlands,
1999
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Subjects: | Chemistry., Physical chemistry., Astrophysics., Atoms., Physics., Physical Chemistry., Atomic, Molecular, Optical and Plasma Physics., Astrophysics and Astroparticles., |
Online Access: | http://dx.doi.org/10.1007/0-306-46938-3 |
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KOHA-OAI-TEST:1707362018-07-30T22:47:18ZThe Role of Rydberg States in Spectroscopy and Photochemistry [electronic resource] : Low and High Rydberg States / Sándorfy, C. editor. SpringerLink (Online service) textDordrecht : Springer Netherlands,1999.engThe aim of this volume is to offer a balanced overview of molecular Rydberg spectroscopy as it has developed over recent decades. Recent evolution has split Rydberg spectroscopy into two apparently distinct fields: the one concerns the low (n=3-5) Rydberg states, the other the very high (typically n>150) Rydberg states. The former is aimed at spectral levels where Rydberg, valence-shell, and intermediate-type states interact, with a variety of photochemical consequences. The latter considers states extremely close to the ionization limit, from whereionization is possible with a very slight amount of additional energy. Recently developed techniques make it possible to produce ions in well-defined electronic, vibrational and rotational states, including states resulting from spin-orbit or Jahn-Teller splitting. It is then possible to study the structure and reactions of such state-selected ions as well as those of the corresponding neutral molecules. These techniques amount to badly needed high resolution photoelectron spectroscopy.Low Rydberg Spectroscopy -- Spectroscopy and Photochemistry of Rydberg States of Small Polyatomic Hydride Molecules -- Ab Initio Configuration Interaction Calculations of Rydberg and Mixed Valence-rydberg States -- Theoretical Study of Circular Dichroism Spectra in the Vacuum-Ultraviolet -- Magnetic Dichroism in the Vacuum Ultraviolet -- Rydberg and Valence States in the Tetra-atomic Molecules B2H2, C2H2 and C2H2+ -- The Rydberg Spectrum Of Aldehydes And Ketones: A comparison using formaldehyde as a benchmark -- The Rydberg Photophysics and Photochemistry of Amines -- Preliminaries -- High Rydberg Spectroscopy -- From Rydbergs To Zeke States -- Lifetimes of Rydberg States in Small Molecules: Fluorescence, Predissociation and Autoionization -- Rotation-Electronic Coupling in Diatomic Rydberg States -- The Dynamics of Electron — Core Interaction in High Molecular Rydberg States -- Dynamics of a Rydberg Molecule in an External Magnetic Field -- Rydberg Atom-Molecule Charge-Exchange Reactions -- On The High Rydberg States Of The Formyl Radical The Dynamics of Vibrational Autoionization in Triatomic Molecules -- Rydberg State Spectroscopy Of The Sh Radical -- Artifacts in PFI-ZEKE Photoelectron Spectroscopy.The aim of this volume is to offer a balanced overview of molecular Rydberg spectroscopy as it has developed over recent decades. Recent evolution has split Rydberg spectroscopy into two apparently distinct fields: the one concerns the low (n=3-5) Rydberg states, the other the very high (typically n>150) Rydberg states. The former is aimed at spectral levels where Rydberg, valence-shell, and intermediate-type states interact, with a variety of photochemical consequences. The latter considers states extremely close to the ionization limit, from whereionization is possible with a very slight amount of additional energy. Recently developed techniques make it possible to produce ions in well-defined electronic, vibrational and rotational states, including states resulting from spin-orbit or Jahn-Teller splitting. It is then possible to study the structure and reactions of such state-selected ions as well as those of the corresponding neutral molecules. These techniques amount to badly needed high resolution photoelectron spectroscopy.Chemistry.Physical chemistry.Astrophysics.Atoms.Physics.Chemistry.Physical Chemistry.Atomic, Molecular, Optical and Plasma Physics.Astrophysics and Astroparticles.Springer eBookshttp://dx.doi.org/10.1007/0-306-46938-3URN:ISBN:9780306469381 |
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Chemistry. Physical chemistry. Astrophysics. Atoms. Physics. Chemistry. Physical Chemistry. Atomic, Molecular, Optical and Plasma Physics. Astrophysics and Astroparticles. Chemistry. Physical chemistry. Astrophysics. Atoms. Physics. Chemistry. Physical Chemistry. Atomic, Molecular, Optical and Plasma Physics. Astrophysics and Astroparticles. |
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Chemistry. Physical chemistry. Astrophysics. Atoms. Physics. Chemistry. Physical Chemistry. Atomic, Molecular, Optical and Plasma Physics. Astrophysics and Astroparticles. Chemistry. Physical chemistry. Astrophysics. Atoms. Physics. Chemistry. Physical Chemistry. Atomic, Molecular, Optical and Plasma Physics. Astrophysics and Astroparticles. Sándorfy, C. editor. SpringerLink (Online service) The Role of Rydberg States in Spectroscopy and Photochemistry [electronic resource] : Low and High Rydberg States / |
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The aim of this volume is to offer a balanced overview of molecular Rydberg spectroscopy as it has developed over recent decades. Recent evolution has split Rydberg spectroscopy into two apparently distinct fields: the one concerns the low (n=3-5) Rydberg states, the other the very high (typically n>150) Rydberg states. The former is aimed at spectral levels where Rydberg, valence-shell, and intermediate-type states interact, with a variety of photochemical consequences. The latter considers states extremely close to the ionization limit, from whereionization is possible with a very slight amount of additional energy. Recently developed techniques make it possible to produce ions in well-defined electronic, vibrational and rotational states, including states resulting from spin-orbit or Jahn-Teller splitting. It is then possible to study the structure and reactions of such state-selected ions as well as those of the corresponding neutral molecules. These techniques amount to badly needed high resolution photoelectron spectroscopy. |
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Chemistry. Physical chemistry. Astrophysics. Atoms. Physics. Chemistry. Physical Chemistry. Atomic, Molecular, Optical and Plasma Physics. Astrophysics and Astroparticles. |
author |
Sándorfy, C. editor. SpringerLink (Online service) |
author_facet |
Sándorfy, C. editor. SpringerLink (Online service) |
author_sort |
Sándorfy, C. editor. |
title |
The Role of Rydberg States in Spectroscopy and Photochemistry [electronic resource] : Low and High Rydberg States / |
title_short |
The Role of Rydberg States in Spectroscopy and Photochemistry [electronic resource] : Low and High Rydberg States / |
title_full |
The Role of Rydberg States in Spectroscopy and Photochemistry [electronic resource] : Low and High Rydberg States / |
title_fullStr |
The Role of Rydberg States in Spectroscopy and Photochemistry [electronic resource] : Low and High Rydberg States / |
title_full_unstemmed |
The Role of Rydberg States in Spectroscopy and Photochemistry [electronic resource] : Low and High Rydberg States / |
title_sort |
role of rydberg states in spectroscopy and photochemistry [electronic resource] : low and high rydberg states / |
publisher |
Dordrecht : Springer Netherlands, |
publishDate |
1999 |
url |
http://dx.doi.org/10.1007/0-306-46938-3 |
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