SEPARATION OF ZINC FROM MANGANESE BY SOLVENT EXTRACTION FROM ACIDIC LEACHATES OF SPENT ZINC-MnO2 DRY CELLS USING NEUTRAL ORGANOPHOSPHORUS EXTRACTANTS
This paper describes a route for recovering manganese and zinc from spent zinc-MnO2 dry cells via acid leaching using sulfuric or hydrochloric acids as leachants. Hydrogen peroxide was added as reductant. Experiments were run at 25-40 °C for 1-3 h. Under the best optimal conditions, over 97.5 wt.% of zinc and manganese were leached by both acids. Zn(II) was best extracted at high free acidity (≥ 1 mol L-1) with tributylphosphate (TBP) or trialkylphosphine oxides (Cyanex 923) diluted in n-heptane. Cyanex 923 was a better extractant than TBP, and the extraction was better performed in hydrochloric leachates. Mn(II) was more co-extracted from hydrochloric leachates and when Cyanex 923 was the extractant, but was easily scrubbed with dilute leachant (~1-2 mol L-1). Zn(II) striping was possible using 5 mol L-1 HCl or H2SO4. Manganese was precipitated as oxalate (MnC2O4.2H2O), free of leached contaminants. High-purity sodium salts of the anions of the leachants were recovered after slow evaporation of the final solution.
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Sociedade Brasileira de Química
2018
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oai:scielo:S0100-404220180007007702018-08-02SEPARATION OF ZINC FROM MANGANESE BY SOLVENT EXTRACTION FROM ACIDIC LEACHATES OF SPENT ZINC-MnO2 DRY CELLS USING NEUTRAL ORGANOPHOSPHORUS EXTRACTANTSIbiapina,Vinício FranciscoAfonso,Júlio CarlosSilva,Rubens Souza daVianna,Cláudio AugustoMantovano,José Luiz Zinc-MnO2 dry cells acid leaching zinc extraction neutral organophosphorus extractants manganese oxalate sodium salts This paper describes a route for recovering manganese and zinc from spent zinc-MnO2 dry cells via acid leaching using sulfuric or hydrochloric acids as leachants. Hydrogen peroxide was added as reductant. Experiments were run at 25-40 °C for 1-3 h. Under the best optimal conditions, over 97.5 wt.% of zinc and manganese were leached by both acids. Zn(II) was best extracted at high free acidity (≥ 1 mol L-1) with tributylphosphate (TBP) or trialkylphosphine oxides (Cyanex 923) diluted in n-heptane. Cyanex 923 was a better extractant than TBP, and the extraction was better performed in hydrochloric leachates. Mn(II) was more co-extracted from hydrochloric leachates and when Cyanex 923 was the extractant, but was easily scrubbed with dilute leachant (~1-2 mol L-1). Zn(II) striping was possible using 5 mol L-1 HCl or H2SO4. Manganese was precipitated as oxalate (MnC2O4.2H2O), free of leached contaminants. High-purity sodium salts of the anions of the leachants were recovered after slow evaporation of the final solution.info:eu-repo/semantics/openAccessSociedade Brasileira de QuímicaQuímica Nova v.41 n.7 20182018-07-01info:eu-repo/semantics/articletext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422018000700770en10.21577/0100-4042.20170249 |
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Ibiapina,Vinício Francisco Afonso,Júlio Carlos Silva,Rubens Souza da Vianna,Cláudio Augusto Mantovano,José Luiz |
spellingShingle |
Ibiapina,Vinício Francisco Afonso,Júlio Carlos Silva,Rubens Souza da Vianna,Cláudio Augusto Mantovano,José Luiz SEPARATION OF ZINC FROM MANGANESE BY SOLVENT EXTRACTION FROM ACIDIC LEACHATES OF SPENT ZINC-MnO2 DRY CELLS USING NEUTRAL ORGANOPHOSPHORUS EXTRACTANTS |
author_facet |
Ibiapina,Vinício Francisco Afonso,Júlio Carlos Silva,Rubens Souza da Vianna,Cláudio Augusto Mantovano,José Luiz |
author_sort |
Ibiapina,Vinício Francisco |
title |
SEPARATION OF ZINC FROM MANGANESE BY SOLVENT EXTRACTION FROM ACIDIC LEACHATES OF SPENT ZINC-MnO2 DRY CELLS USING NEUTRAL ORGANOPHOSPHORUS EXTRACTANTS |
title_short |
SEPARATION OF ZINC FROM MANGANESE BY SOLVENT EXTRACTION FROM ACIDIC LEACHATES OF SPENT ZINC-MnO2 DRY CELLS USING NEUTRAL ORGANOPHOSPHORUS EXTRACTANTS |
title_full |
SEPARATION OF ZINC FROM MANGANESE BY SOLVENT EXTRACTION FROM ACIDIC LEACHATES OF SPENT ZINC-MnO2 DRY CELLS USING NEUTRAL ORGANOPHOSPHORUS EXTRACTANTS |
title_fullStr |
SEPARATION OF ZINC FROM MANGANESE BY SOLVENT EXTRACTION FROM ACIDIC LEACHATES OF SPENT ZINC-MnO2 DRY CELLS USING NEUTRAL ORGANOPHOSPHORUS EXTRACTANTS |
title_full_unstemmed |
SEPARATION OF ZINC FROM MANGANESE BY SOLVENT EXTRACTION FROM ACIDIC LEACHATES OF SPENT ZINC-MnO2 DRY CELLS USING NEUTRAL ORGANOPHOSPHORUS EXTRACTANTS |
title_sort |
separation of zinc from manganese by solvent extraction from acidic leachates of spent zinc-mno2 dry cells using neutral organophosphorus extractants |
description |
This paper describes a route for recovering manganese and zinc from spent zinc-MnO2 dry cells via acid leaching using sulfuric or hydrochloric acids as leachants. Hydrogen peroxide was added as reductant. Experiments were run at 25-40 °C for 1-3 h. Under the best optimal conditions, over 97.5 wt.% of zinc and manganese were leached by both acids. Zn(II) was best extracted at high free acidity (≥ 1 mol L-1) with tributylphosphate (TBP) or trialkylphosphine oxides (Cyanex 923) diluted in n-heptane. Cyanex 923 was a better extractant than TBP, and the extraction was better performed in hydrochloric leachates. Mn(II) was more co-extracted from hydrochloric leachates and when Cyanex 923 was the extractant, but was easily scrubbed with dilute leachant (~1-2 mol L-1). Zn(II) striping was possible using 5 mol L-1 HCl or H2SO4. Manganese was precipitated as oxalate (MnC2O4.2H2O), free of leached contaminants. High-purity sodium salts of the anions of the leachants were recovered after slow evaporation of the final solution. |
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Sociedade Brasileira de Química |
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2018 |
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http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422018000700770 |
work_keys_str_mv |
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