Degradative studies on a soil humin fraction-sequential degradation of inherited humin

8 pages, 3 figures, 3 tables, 23 references.

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Main Authors: Almendros Martín, Gonzalo, González-Vila, Francisco Javier
Format: artículo biblioteca
Language:English
Published: Pergamon Press 1987
Online Access:http://hdl.handle.net/10261/51365
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spelling dig-irnas-es-10261-513652019-08-06T09:27:06Z Degradative studies on a soil humin fraction-sequential degradation of inherited humin Almendros Martín, Gonzalo González-Vila, Francisco Javier 8 pages, 3 figures, 3 tables, 23 references. Degradation products of soil humin preparations from three different soil types were studied. Inherited humin was isolated by ultrasonic treatment and densimetry of the heavy fraction of soil, and purified by treatment with dilute alkali and acid and exhaustive lipid extraction. These purified humins, which represented 10-26% of the total soil C (34-55% of total alkali-insoluble humified C), were degraded with potassium persulfate followed by alkaline permanganate oxidation. The degradation products obtained (identified by GC-MS as methyl derivatives) were fatty acids, dicarboxylic aliphatic acids, benzenecarboxylic acids, phenolic acids and alkanes. An unexpectedly high proportion of polymethylene compounds (mainly fatty acids) were observed in the humins of the three soils, in both loosely and strongly associated forms. It is considered that these aliphatic chains are stable humin constituents, physically or chemically associated with a highly oxidized, demethoxylated and disordered matrix entrapping a significant proportion of non-polar compounds. Some of the aliphatic components seem to be inherited from cuticular waxes of higher plants, but it is tentatively suggested that during the microbial reworking of lignins the lipid polymers were altered, then contributing to the formation of humin. Peer reviewed 2012-06-12T10:21:41Z 2012-06-12T10:21:41Z 1987 artículo http://purl.org/coar/resource_type/c_6501 Soil Biology and Biochemistry 19(5): 513-520 (1987) 0038-0717 http://hdl.handle.net/10261/51365 en open Pergamon Press
institution IRNAS ES
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country España
countrycode ES
component Bibliográfico
access En linea
databasecode dig-irnas-es
tag biblioteca
region Europa del Sur
libraryname Biblioteca del IRNAS España
language English
description 8 pages, 3 figures, 3 tables, 23 references.
format artículo
author Almendros Martín, Gonzalo
González-Vila, Francisco Javier
spellingShingle Almendros Martín, Gonzalo
González-Vila, Francisco Javier
Degradative studies on a soil humin fraction-sequential degradation of inherited humin
author_facet Almendros Martín, Gonzalo
González-Vila, Francisco Javier
author_sort Almendros Martín, Gonzalo
title Degradative studies on a soil humin fraction-sequential degradation of inherited humin
title_short Degradative studies on a soil humin fraction-sequential degradation of inherited humin
title_full Degradative studies on a soil humin fraction-sequential degradation of inherited humin
title_fullStr Degradative studies on a soil humin fraction-sequential degradation of inherited humin
title_full_unstemmed Degradative studies on a soil humin fraction-sequential degradation of inherited humin
title_sort degradative studies on a soil humin fraction-sequential degradation of inherited humin
publisher Pergamon Press
publishDate 1987
url http://hdl.handle.net/10261/51365
work_keys_str_mv AT almendrosmartingonzalo degradativestudiesonasoilhuminfractionsequentialdegradationofinheritedhumin
AT gonzalezvilafranciscojavier degradativestudiesonasoilhuminfractionsequentialdegradationofinheritedhumin
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