Microplastic removal in managed aquifer recharge using wastewater effluent

Microplastic (MP) pollution has emerged as a pressing environmental issue, with its impacts on ecosystems and human health yet to be fully understood. This study aims to investigate the presence and distribution of MPs in the soil of a managed aquifer recharge (MAR) system, built with different reactive barriers of natural materials and irrigated with the secondary effluent of a wastewater treatment plant (WWTP). MPs were extracted from reactive barrier material following an approach based on the density separation of MPs with posterior oxidant digestion, combined with visual and chemical characterisation by Fourier-Transform Infrared Spectroscopy (FTIR). The results revealed the widespread occurrence of MPs in the MAR soil samples. MPs concentration in the different barrier materials ranged from 60 to 236 n kg-1. The most dominant morphologies were fragments (60%) and fibers (17%), and the most abundant colour was white (51%), followed by transparent MPs (20%). Polypropylene (PP) was detected in all the samples with an abundance of 47%, followed by polyethylene (PE, 34%). The interplay of barrier composition significantly influences the retention of MPs, with compost (T5) and woodchips (T4) exhibiting the most notable retention rates. Remarkably, the outer layers of the reactive barriers display superior retention compared to the deeper layers. The findings of this study demonstrate the good performance of the MAR system in retaining MPs and contribute to the growing body of knowledge on MPs pollution in freshwater systems while providing insights into the dynamics of MPs transport and accumulation in soil. Such information can inform the development of effective wastewater management strategies to mitigate the impacts of these pollutants on water resources and safeguard the environment.

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Bibliographic Details
Main Authors: Contreras-Llin, Albert, Díaz-Cruz, M. Silvia
Other Authors: 0000-0001-8673-896X
Format: artículo biblioteca
Language:English
Published: Elsevier 2023-11-27
Subjects:Water quality, Microplastics, Polymer identification, Reactive barriers, Retention, Wastewater, http://metadata.un.org/sdg/3, http://metadata.un.org/sdg/6, Ensure healthy lives and promote well-being for all at all ages, Ensure availability and sustainable management of water and sanitation for all,
Online Access:http://hdl.handle.net/10261/340374
https://api.elsevier.com/content/abstract/scopus_id/85178117922
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spelling dig-idaea-es-10261-3403742024-05-16T20:44:35Z Microplastic removal in managed aquifer recharge using wastewater effluent Contreras-Llin, Albert Díaz-Cruz, M. Silvia 0000-0001-8673-896X Water quality Microplastics Polymer identification Reactive barriers Retention Wastewater http://metadata.un.org/sdg/3 http://metadata.un.org/sdg/6 Ensure healthy lives and promote well-being for all at all ages Ensure availability and sustainable management of water and sanitation for all Microplastic (MP) pollution has emerged as a pressing environmental issue, with its impacts on ecosystems and human health yet to be fully understood. This study aims to investigate the presence and distribution of MPs in the soil of a managed aquifer recharge (MAR) system, built with different reactive barriers of natural materials and irrigated with the secondary effluent of a wastewater treatment plant (WWTP). MPs were extracted from reactive barrier material following an approach based on the density separation of MPs with posterior oxidant digestion, combined with visual and chemical characterisation by Fourier-Transform Infrared Spectroscopy (FTIR). The results revealed the widespread occurrence of MPs in the MAR soil samples. MPs concentration in the different barrier materials ranged from 60 to 236 n kg-1. The most dominant morphologies were fragments (60%) and fibers (17%), and the most abundant colour was white (51%), followed by transparent MPs (20%). Polypropylene (PP) was detected in all the samples with an abundance of 47%, followed by polyethylene (PE, 34%). The interplay of barrier composition significantly influences the retention of MPs, with compost (T5) and woodchips (T4) exhibiting the most notable retention rates. Remarkably, the outer layers of the reactive barriers display superior retention compared to the deeper layers. The findings of this study demonstrate the good performance of the MAR system in retaining MPs and contribute to the growing body of knowledge on MPs pollution in freshwater systems while providing insights into the dynamics of MPs transport and accumulation in soil. Such information can inform the development of effective wastewater management strategies to mitigate the impacts of these pollutants on water resources and safeguard the environment. The authors are grateful to Water JPI and the Agencia Estatal de Investigación (AEI) for the project MARadentro (PCI 2019-103603), and to EC for the REMAR project (REMAR- LIFE20 ENV/ES/000284). MSDC and ACL also acknowledge Generalitat de Catalunya for the 2021 SGR 00753. Peer reviewed 2023-12-11T08:50:58Z 2023-12-11T08:50:58Z 2023-11-27 artículo http://purl.org/coar/resource_type/c_6501 Environmental Pollution 342: 122967 (2023) 02697491 http://hdl.handle.net/10261/340374 10.1016/j.envpol.2023.122967 38030113 2-s2.0-85178117922 https://api.elsevier.com/content/abstract/scopus_id/85178117922 en Environmental pollution (Barking, Essex : 1987) Publisher's version https://doi.org/10.1016/j.envpol.2023.122967 Sí open Elsevier
institution IDAEA ES
collection DSpace
country España
countrycode ES
component Bibliográfico
access En linea
databasecode dig-idaea-es
tag biblioteca
region Europa del Sur
libraryname Biblioteca del IDAEA España
language English
topic Water quality
Microplastics
Polymer identification
Reactive barriers
Retention
Wastewater
http://metadata.un.org/sdg/3
http://metadata.un.org/sdg/6
Ensure healthy lives and promote well-being for all at all ages
Ensure availability and sustainable management of water and sanitation for all
Water quality
Microplastics
Polymer identification
Reactive barriers
Retention
Wastewater
http://metadata.un.org/sdg/3
http://metadata.un.org/sdg/6
Ensure healthy lives and promote well-being for all at all ages
Ensure availability and sustainable management of water and sanitation for all
spellingShingle Water quality
Microplastics
Polymer identification
Reactive barriers
Retention
Wastewater
http://metadata.un.org/sdg/3
http://metadata.un.org/sdg/6
Ensure healthy lives and promote well-being for all at all ages
Ensure availability and sustainable management of water and sanitation for all
Water quality
Microplastics
Polymer identification
Reactive barriers
Retention
Wastewater
http://metadata.un.org/sdg/3
http://metadata.un.org/sdg/6
Ensure healthy lives and promote well-being for all at all ages
Ensure availability and sustainable management of water and sanitation for all
Contreras-Llin, Albert
Díaz-Cruz, M. Silvia
Microplastic removal in managed aquifer recharge using wastewater effluent
description Microplastic (MP) pollution has emerged as a pressing environmental issue, with its impacts on ecosystems and human health yet to be fully understood. This study aims to investigate the presence and distribution of MPs in the soil of a managed aquifer recharge (MAR) system, built with different reactive barriers of natural materials and irrigated with the secondary effluent of a wastewater treatment plant (WWTP). MPs were extracted from reactive barrier material following an approach based on the density separation of MPs with posterior oxidant digestion, combined with visual and chemical characterisation by Fourier-Transform Infrared Spectroscopy (FTIR). The results revealed the widespread occurrence of MPs in the MAR soil samples. MPs concentration in the different barrier materials ranged from 60 to 236 n kg-1. The most dominant morphologies were fragments (60%) and fibers (17%), and the most abundant colour was white (51%), followed by transparent MPs (20%). Polypropylene (PP) was detected in all the samples with an abundance of 47%, followed by polyethylene (PE, 34%). The interplay of barrier composition significantly influences the retention of MPs, with compost (T5) and woodchips (T4) exhibiting the most notable retention rates. Remarkably, the outer layers of the reactive barriers display superior retention compared to the deeper layers. The findings of this study demonstrate the good performance of the MAR system in retaining MPs and contribute to the growing body of knowledge on MPs pollution in freshwater systems while providing insights into the dynamics of MPs transport and accumulation in soil. Such information can inform the development of effective wastewater management strategies to mitigate the impacts of these pollutants on water resources and safeguard the environment.
author2 0000-0001-8673-896X
author_facet 0000-0001-8673-896X
Contreras-Llin, Albert
Díaz-Cruz, M. Silvia
format artículo
topic_facet Water quality
Microplastics
Polymer identification
Reactive barriers
Retention
Wastewater
http://metadata.un.org/sdg/3
http://metadata.un.org/sdg/6
Ensure healthy lives and promote well-being for all at all ages
Ensure availability and sustainable management of water and sanitation for all
author Contreras-Llin, Albert
Díaz-Cruz, M. Silvia
author_sort Contreras-Llin, Albert
title Microplastic removal in managed aquifer recharge using wastewater effluent
title_short Microplastic removal in managed aquifer recharge using wastewater effluent
title_full Microplastic removal in managed aquifer recharge using wastewater effluent
title_fullStr Microplastic removal in managed aquifer recharge using wastewater effluent
title_full_unstemmed Microplastic removal in managed aquifer recharge using wastewater effluent
title_sort microplastic removal in managed aquifer recharge using wastewater effluent
publisher Elsevier
publishDate 2023-11-27
url http://hdl.handle.net/10261/340374
https://api.elsevier.com/content/abstract/scopus_id/85178117922
work_keys_str_mv AT contrerasllinalbert microplasticremovalinmanagedaquiferrechargeusingwastewatereffluent
AT diazcruzmsilvia microplasticremovalinmanagedaquiferrechargeusingwastewatereffluent
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