Contemporary Problems in Carbonium Ion Chemistry I/II [electronic resource] /

Contemporary Problems in Carbonium Ion Chemistry I/II [electronic resource] /

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In 1965 a book by P. Bartlett appeared under the title "The Nonclassical Ions" 1). The book is a collection of papers reprinted from various journals. The many reviews that have appeared since 2-22) are either antiquated (the book published in 1972 12) covers the literature mainly before 1968) or relatively biased (e.g., 3.4,10» on brief 2, 7,11). This review attempts to discuss the various points of view on the "nonclassical" carbocations. The main point is to establish the relative role of "nonclassical" and "classical" ions in various chemical processes. The author has followed P. Bartlett's advice 1) that when setting forth the achievements of the human mind one should see how we came to the modern understanding of a given problem (" ... how we know what we know"). The theory of "nonclassical" ions offers an explanation of many unique chemical, stereochemical and kinetic peculiarities of bicyclic compounds. It has expanded our knowledge on chemical bonds in carbocations by introducing electron-deficient bonds (as in boron hydrides). It has accounted for many rearrangements of stable cations. As a "side" result our knowledge has been extended about ionization processes in a solution, as well as about stereochemical methods. 2 Main Terms of Nonclassical Carbocations In 1939 Hevell, Salas and Wilson 23) assumed an intermediate, "bridge" ion 2 to be formed when camphene hydrochloride 1 is rearranged into isobornyl chloride 3. This happened 17 years after Meerwein first postulated the intermediate formation of "carbonium" ions in chemical reactions.

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Main Authors: Rees, Ch. editor., SpringerLink (Online service)
Format: Texto biblioteca
Language:eng
Published: Berlin, Heidelberg : Springer Berlin Heidelberg : Imprint: Springer, 1984
Subjects:Chemistry., Physical chemistry., Chemistry, Physical and theoretical., Theoretical and Computational Chemistry., Physical Chemistry.,
Online Access:http://dx.doi.org/10.1007/978-3-662-15286-7
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spelling KOHA-OAI-TEST:1938212018-07-30T23:18:57ZContemporary Problems in Carbonium Ion Chemistry I/II [electronic resource] / Rees, Ch. editor. SpringerLink (Online service) textBerlin, Heidelberg : Springer Berlin Heidelberg : Imprint: Springer,1984.engIn 1965 a book by P. Bartlett appeared under the title "The Nonclassical Ions" 1). The book is a collection of papers reprinted from various journals. The many reviews that have appeared since 2-22) are either antiquated (the book published in 1972 12) covers the literature mainly before 1968) or relatively biased (e.g., 3.4,10» on brief 2, 7,11). This review attempts to discuss the various points of view on the "nonclassical" carbocations. The main point is to establish the relative role of "nonclassical" and "classical" ions in various chemical processes. The author has followed P. Bartlett's advice 1) that when setting forth the achievements of the human mind one should see how we came to the modern understanding of a given problem (" ... how we know what we know"). The theory of "nonclassical" ions offers an explanation of many unique chemical, stereochemical and kinetic peculiarities of bicyclic compounds. It has expanded our knowledge on chemical bonds in carbocations by introducing electron-deficient bonds (as in boron hydrides). It has accounted for many rearrangements of stable cations. As a "side" result our knowledge has been extended about ionization processes in a solution, as well as about stereochemical methods. 2 Main Terms of Nonclassical Carbocations In 1939 Hevell, Salas and Wilson 23) assumed an intermediate, "bridge" ion 2 to be formed when camphene hydrochloride 1 is rearranged into isobornyl chloride 3. This happened 17 years after Meerwein first postulated the intermediate formation of "carbonium" ions in chemical reactions.Nonclassical Carbocations -- Rearrangements of Carbocations by 1,2-Shifts -- Author Index Volumes 101–117.In 1965 a book by P. Bartlett appeared under the title "The Nonclassical Ions" 1). The book is a collection of papers reprinted from various journals. The many reviews that have appeared since 2-22) are either antiquated (the book published in 1972 12) covers the literature mainly before 1968) or relatively biased (e.g., 3.4,10» on brief 2, 7,11). This review attempts to discuss the various points of view on the "nonclassical" carbocations. The main point is to establish the relative role of "nonclassical" and "classical" ions in various chemical processes. The author has followed P. Bartlett's advice 1) that when setting forth the achievements of the human mind one should see how we came to the modern understanding of a given problem (" ... how we know what we know"). The theory of "nonclassical" ions offers an explanation of many unique chemical, stereochemical and kinetic peculiarities of bicyclic compounds. It has expanded our knowledge on chemical bonds in carbocations by introducing electron-deficient bonds (as in boron hydrides). It has accounted for many rearrangements of stable cations. As a "side" result our knowledge has been extended about ionization processes in a solution, as well as about stereochemical methods. 2 Main Terms of Nonclassical Carbocations In 1939 Hevell, Salas and Wilson 23) assumed an intermediate, "bridge" ion 2 to be formed when camphene hydrochloride 1 is rearranged into isobornyl chloride 3. This happened 17 years after Meerwein first postulated the intermediate formation of "carbonium" ions in chemical reactions.Chemistry.Physical chemistry.Chemistry, Physical and theoretical.Chemistry.Theoretical and Computational Chemistry.Physical Chemistry.Springer eBookshttp://dx.doi.org/10.1007/978-3-662-15286-7URN:ISBN:9783662152867
institution COLPOS
collection Koha
country México
countrycode MX
component Bibliográfico
access En linea
En linea
databasecode cat-colpos
tag biblioteca
region America del Norte
libraryname Departamento de documentación y biblioteca de COLPOS
language eng
topic Chemistry.
Physical chemistry.
Chemistry, Physical and theoretical.
Chemistry.
Theoretical and Computational Chemistry.
Physical Chemistry.
Chemistry.
Physical chemistry.
Chemistry, Physical and theoretical.
Chemistry.
Theoretical and Computational Chemistry.
Physical Chemistry.
spellingShingle Chemistry.
Physical chemistry.
Chemistry, Physical and theoretical.
Chemistry.
Theoretical and Computational Chemistry.
Physical Chemistry.
Chemistry.
Physical chemistry.
Chemistry, Physical and theoretical.
Chemistry.
Theoretical and Computational Chemistry.
Physical Chemistry.
Rees, Ch. editor.
SpringerLink (Online service)
Contemporary Problems in Carbonium Ion Chemistry I/II [electronic resource] /
description In 1965 a book by P. Bartlett appeared under the title "The Nonclassical Ions" 1). The book is a collection of papers reprinted from various journals. The many reviews that have appeared since 2-22) are either antiquated (the book published in 1972 12) covers the literature mainly before 1968) or relatively biased (e.g., 3.4,10» on brief 2, 7,11). This review attempts to discuss the various points of view on the "nonclassical" carbocations. The main point is to establish the relative role of "nonclassical" and "classical" ions in various chemical processes. The author has followed P. Bartlett's advice 1) that when setting forth the achievements of the human mind one should see how we came to the modern understanding of a given problem (" ... how we know what we know"). The theory of "nonclassical" ions offers an explanation of many unique chemical, stereochemical and kinetic peculiarities of bicyclic compounds. It has expanded our knowledge on chemical bonds in carbocations by introducing electron-deficient bonds (as in boron hydrides). It has accounted for many rearrangements of stable cations. As a "side" result our knowledge has been extended about ionization processes in a solution, as well as about stereochemical methods. 2 Main Terms of Nonclassical Carbocations In 1939 Hevell, Salas and Wilson 23) assumed an intermediate, "bridge" ion 2 to be formed when camphene hydrochloride 1 is rearranged into isobornyl chloride 3. This happened 17 years after Meerwein first postulated the intermediate formation of "carbonium" ions in chemical reactions.
format Texto
topic_facet Chemistry.
Physical chemistry.
Chemistry, Physical and theoretical.
Chemistry.
Theoretical and Computational Chemistry.
Physical Chemistry.
author Rees, Ch. editor.
SpringerLink (Online service)
author_facet Rees, Ch. editor.
SpringerLink (Online service)
author_sort Rees, Ch. editor.
title Contemporary Problems in Carbonium Ion Chemistry I/II [electronic resource] /
title_short Contemporary Problems in Carbonium Ion Chemistry I/II [electronic resource] /
title_full Contemporary Problems in Carbonium Ion Chemistry I/II [electronic resource] /
title_fullStr Contemporary Problems in Carbonium Ion Chemistry I/II [electronic resource] /
title_full_unstemmed Contemporary Problems in Carbonium Ion Chemistry I/II [electronic resource] /
title_sort contemporary problems in carbonium ion chemistry i/ii [electronic resource] /
publisher Berlin, Heidelberg : Springer Berlin Heidelberg : Imprint: Springer,
publishDate 1984
url http://dx.doi.org/10.1007/978-3-662-15286-7
work_keys_str_mv AT reescheditor contemporaryproblemsincarboniumionchemistryiiielectronicresource
AT springerlinkonlineservice contemporaryproblemsincarboniumionchemistryiiielectronicresource
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