AN ELECTROCHEMICAL STUDY OF THE COBALT ELECTRODEPOSITION ONTO A CARBON FIBER ULTRAMICROELECTRODE
ABSTRACT A kinetic study of the cobalt electrodeposition onto a carbon fiber ultramicroelectrode of 11 μm of diameter was conducted in overpotential conditions from an aqueous solution containing 0.01 M CoCl2 + 0.1 M NH4Cl. From the voltamperometric and chronoamperometric studies, it was found that the value of the diffusion coefficient is 1.2x10−5 cm2 s−1. The analysis of the current density transients suggests that cobalt electrodeposition onto a carbon fiber electrode follows an instantaneous nucleation process controlled by spherical diffusion mass transport. Also, the number of active nucleation sites increases as the applied potential decreases.
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Main Authors: | Corona-Castro,Jair A., Álvarez-Romero,Giaan A., Rivera,Margarita, Rios-Reyes,Clara H., Bañuelos-García,L.E., García-Sánchez,E., Mendoza-Huizar,Luis H. |
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Format: | Digital revista |
Language: | English |
Published: |
Sociedad Chilena de Química
2022
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Online Access: | http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072022000205500 |
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