A water soluble 3-n-propyl-1-azonia-4-azabicyclo[2.2.2]octanechloride silsesquioxane grafted onto Al/SiO2 surface: chromium adsorption study

The water soluble material, 3-n-propyl-1-azonia-4-azabicyclo[2.2.2]octanechloride silsesquioxane (dabcosil silsesquioxane) was obtained. The dabcosil silsesquioxane was grafted onto a silica surface, previously modified with aluminum oxide. The resulting solid, dabcosil-Al/SiO2, presents 0.15 mmol of dabco groups per gram of material. The product of the grafting reaction was analyzed by infrared spectroscopy and N2 adsorption-desorption isotherms. The dabcosil-Al/SiO2 material was used as sorbent for chromium (VI) adsorption in aqueous solution.

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Bibliographic Details
Main Authors: Arenas,L. T., Simon,N. M., Gushikem,Y., Costa,T. M. H., Lima,E. C., Benvenutti,E. V.
Format: Digital revista
Language:English
Published: Fundação Editora da Universidade Estadual Paulista Júlio de Mesquita Filho - UNESP 2006
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-46702006000200008
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