Sulfur–Phenolate Exchange : SuFEx-Derived Dynamic Covalent Reactions and Degradation of SuFEx Polymers
The products of the SuFEx reaction between sulfonimidoyl fluorides and phenols, sulfonimidates, are shown to display dynamic covalent chemistry with other phenols. This reaction was shown to be enantiospecific, finished in minutes at room temperature in high yields, and useful for both asymmetric synthesis and sustainable polymer production. Its wide scope further extends the usefulness of SuFEx and related click chemistries.
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| Main Authors: | , , , , , , , , |
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| Format: | Article/Letter to editor biblioteca |
| Language: | English |
| Subjects: | Click Chemistry, Enantiospecific Suphenex, Kinetics, Reaction Mechanisms, Sulfur–Phenolate Exchange, |
| Online Access: | https://research.wur.nl/en/publications/sulfurphenolate-exchange-sufex-derived-dynamic-covalent-reactions |
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