Dynamic Effect of Fresh and Aged Biochar on the Behavior of the Herbicide Mesotrione in Soils
10 páginas.- 6 figuras.- 5 tablas.- 57 referencias.- The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.jafc.9b02618
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American Chemical Society
2019-08-28
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Subjects: | Biodegradation, Bound residues, Desorption, Leaching, Organic amendments, Soil weathering, |
Online Access: | http://hdl.handle.net/10261/200403 http://dx.doi.org/10.13039/501100004837 |
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dig-irnas-es-10261-2004032020-08-28T04:31:06Z Dynamic Effect of Fresh and Aged Biochar on the Behavior of the Herbicide Mesotrione in Soils Gámiz, B. Velarde Muñoz, Pilar Spokas, K. A. Cox, L. Ministerio de Ciencia e Innovación (España) Ministerio de Ciencia, Innovación y Universidades (España) Gámiz, B. [0000-0002-7244-778X] Cox, L. [0000-0003-2113-4780] Biodegradation Bound residues Desorption Leaching Organic amendments Soil weathering 10 páginas.- 6 figuras.- 5 tablas.- 57 referencias.- The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.jafc.9b02618 In this study, we assessed the sorption, dissipation, and leaching of the herbicide mesotrione in soil amended with fresh and field-aged biochars, when added to the soil. The aging process was performed by burying the fresh biochar at 10 cm depth in three soils located in different points across the USA [Wisconsin (ABC_WI), Idaho (ABC_ID), and South Carolina (ABC_SC)] for six months. ABC_ID and ABC_SC slightly increased the sorption of mesotrione in soils, whereas ABC_WI removed greater amounts of herbicide from the solution. This was attributed to differences in water-soluble components and metal content of this aged biochar. Consequently, the persistence of the herbicide in the amended soils with fresh biochar and ABC_ID and ABC_SC were similar to that in unamended soils, while ABC_WI slightly increased mesotrione half-life. Differences between treatments were detected in leaching studies although no direct relationship with the dissipation batch studies was observed. Mesotrione leaching could not be detected in soil columns amended with ABC_WI and was high for the rest of treatments. The outcomes from this work demonstrate that temporal variability of biochar sorption capacities due to soil exposure can occur altering mesotrione’s behavior in biochar-amended soils. This work was financed by the Spanish Ministry of Science, Innovation and Universities (MICINN Project AGL2016-77821-R). B.G. thanks MICINN for her Juan de la Cierva Incorporacion postdoctoral contract (IJCI-2015-23309). Peer reviewed 2020-02-12T11:07:46Z 2020-02-12T11:07:46Z 2019-08-28 artículo http://purl.org/coar/resource_type/c_6501 Journal of Agricultural and Food Chemistry 67(34): 9450-9459 (2019) 0021-8561 http://hdl.handle.net/10261/200403 10.1021/acs.jafc.9b02618 http://dx.doi.org/10.13039/501100004837 en #PLACEHOLDER_PARENT_METADATA_VALUE# #PLACEHOLDER_PARENT_METADATA_VALUE# info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/AGL2016-77821-R info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/IJCI-2015-23309 Postprint http://dx.doi.org/10.1021/acs.jafc.9b02618 Sí open American Chemical Society |
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Biodegradation Bound residues Desorption Leaching Organic amendments Soil weathering Biodegradation Bound residues Desorption Leaching Organic amendments Soil weathering |
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Biodegradation Bound residues Desorption Leaching Organic amendments Soil weathering Biodegradation Bound residues Desorption Leaching Organic amendments Soil weathering Gámiz, B. Velarde Muñoz, Pilar Spokas, K. A. Cox, L. Dynamic Effect of Fresh and Aged Biochar on the Behavior of the Herbicide Mesotrione in Soils |
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10 páginas.- 6 figuras.- 5 tablas.- 57 referencias.- The Supporting Information is available free of charge on the
ACS Publications website at DOI: 10.1021/acs.jafc.9b02618 |
author2 |
Ministerio de Ciencia e Innovación (España) |
author_facet |
Ministerio de Ciencia e Innovación (España) Gámiz, B. Velarde Muñoz, Pilar Spokas, K. A. Cox, L. |
format |
artículo |
topic_facet |
Biodegradation Bound residues Desorption Leaching Organic amendments Soil weathering |
author |
Gámiz, B. Velarde Muñoz, Pilar Spokas, K. A. Cox, L. |
author_sort |
Gámiz, B. |
title |
Dynamic Effect of Fresh and Aged Biochar on the Behavior of the Herbicide Mesotrione in Soils |
title_short |
Dynamic Effect of Fresh and Aged Biochar on the Behavior of the Herbicide Mesotrione in Soils |
title_full |
Dynamic Effect of Fresh and Aged Biochar on the Behavior of the Herbicide Mesotrione in Soils |
title_fullStr |
Dynamic Effect of Fresh and Aged Biochar on the Behavior of the Herbicide Mesotrione in Soils |
title_full_unstemmed |
Dynamic Effect of Fresh and Aged Biochar on the Behavior of the Herbicide Mesotrione in Soils |
title_sort |
dynamic effect of fresh and aged biochar on the behavior of the herbicide mesotrione in soils |
publisher |
American Chemical Society |
publishDate |
2019-08-28 |
url |
http://hdl.handle.net/10261/200403 http://dx.doi.org/10.13039/501100004837 |
work_keys_str_mv |
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