Nitroamine radicals as intermediates in the functionalization of non-activated carbon atoms
Photolysis of N-iodonitroamines generated in situ from the steroidal nitroamines 6β-nitroamino-5α-cholestan-3β-ol acetate, 6β-nitroamino-5α-cholestane-3β,5α-diol diacetate, and 20R-nitroaminopregn-5-en-3-ol acetate removes hydrogen atoms from the Me-18 and Me-19 groups to give 6β-,19-N-nitroepinino-5α-cholestan-3β-ol acetate, 6β,19-N-nitroepinino-5α-cholestane-3β5α-diol diacetate, and 18,20R-N-nitroepiminopregn-5-en-3β-ol acetate.
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| Main Authors: | , , , |
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| Other Authors: | |
| Format: | artículo biblioteca |
| Language: | English |
| Published: |
Royal Society of Chemistry (UK)
1980
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| Online Access: | http://hdl.handle.net/10261/17572 http://dx.doi.org/10.13039/501100003767 |
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