Rapid determination of antibiotic residues in cereals by liquid chromatography triple mass spectrometry

Rapid determination of antibiotic residues in cereals by liquid chromatography triple mass spectrometry

11 Pág.

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Main Authors: Albero Romano, María Beatriz, Tadeo Lluch, José Luis, Miguel Gómez, María Esther, Pérez Martín, Rosa Ana
Other Authors: Ministerio de Economía, Industria y Competitividad (España)
Format: artículo biblioteca
Language:English
Published: Springer 2019-09-01
Subjects:Analysis, Antibiotics, Grains, LC-MS/MS, Uptake,
Online Access:http://hdl.handle.net/10261/341355
http://dx.doi.org/10.13039/501100010198
https://api.elsevier.com/content/abstract/scopus_id/85068847210
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spelling dig-inia-es-10261-3413552024-05-17T20:36:22Z Rapid determination of antibiotic residues in cereals by liquid chromatography triple mass spectrometry Albero Romano, María Beatriz Tadeo Lluch, José Luis Miguel Gómez, María Esther Pérez Martín, Rosa Ana Ministerio de Economía, Industria y Competitividad (España) Albero Romano, María Beatriz [0000-0002-6470-5232] Tadeo Lluch, José Luis [0000-0002-9810-7249] Miguel Gómez, María Esther [0000-0002-3010-2724] Pérez Martín, Rosa Ana [0000-0001-8076-9167] Analysis Antibiotics Grains LC-MS/MS Uptake 11 Pág. Antibiotics may be present in agricultural soils through the application of organic amendments as fertilizers or by irrigation of fields with recycled water. As a result of these agricultural practices, antibiotics in soil can lead to their uptake by plants, entering in this way the food chain. Studies on the levels of antibiotics in cereal samples are scarce in the available literature. In this work, an analytical method was developed for the determination of 19 antibiotics (fluoroquinolones, sulfonamides, tetracyclines, and lincosamides) in four types of cereal grains (wheat, barley, rice, and oat). Ultrasound-assisted matrix solid-phase dispersion was selected as extraction technique with recoveries of target analytes ranging from 73 to 127% for the four cereals analyzed. Limits of quantification obtained ranged from 0.8 to 5.8 ng g-1. Compared with methods described for the analysis of antibiotics in cereals, the developed method uses a lower volume of extraction solvent and very good recoveries were obtained for all compounds. The validated method was applied to the analysis of different types of cereals samples, harvested from agricultural fields or purchased from local supermarkets. The analysis of the five cereal samples grown in fields with 3 years of consecutive organic amendments revealed that none of the nineteen antibiotics selected were found in any sample. Eleven commercial samples of cereals of different types and presentations were analyzed and enrofloxacin was detected in one rice sample; the presence of enrofloxacin in cereals or its incorporation into crops from soil or water not previously reported. Graphical abstract. The authors wish to thank the Spanish Ministry of Economy, Industry and Competitiveness for financial support, project (RTA2014-00012C03). The authors would like to thank Dr. M? Carmen Lobo Bedmar (IMIDRA) and Dr. Jose Luis Tenorio (INIA) for the cereal samples grown in the agricultural fields and the wheat grown in the experimental farm ?La Canaleja? (Madrid), respectively. Peer reviewed 2023-12-27T10:44:32Z 2023-12-27T10:44:32Z 2019-09-01 artículo http://purl.org/coar/resource_type/c_6501 Analytical and Bioanalytical Chemistry 411(23): 6129-6139 (2019) 1618-2642 http://hdl.handle.net/10261/341355 10.1007/s00216-019-02003-w 1618-2650 http://dx.doi.org/10.13039/501100010198 31278554 2-s2.0-85068847210 https://api.elsevier.com/content/abstract/scopus_id/85068847210 en #PLACEHOLDER_PARENT_METADATA_VALUE# info:eu-repo/grantAgreement/MINECO//RTA2014-00012-C03-01/ES/Determinación de los niveles y evaluación del comportamiento ambiental de antibióticos y otros contaminantes emergentes en enmiendas orgánicas, en el suelo y en el cultivo tras la aplicación de las enmiendas/ Departamento de Medio Ambiente y Agronomía​ Publisher's version https://doi.org/10.1007/s00216-019-02003-w Sí open Springer
institution INIA ES
collection DSpace
country España
countrycode ES
component Bibliográfico
access En linea
databasecode dig-inia-es
tag biblioteca
region Europa del Sur
libraryname Biblioteca del INIA España
language English
topic Analysis
Antibiotics
Grains
LC-MS/MS
Uptake
Analysis
Antibiotics
Grains
LC-MS/MS
Uptake
spellingShingle Analysis
Antibiotics
Grains
LC-MS/MS
Uptake
Analysis
Antibiotics
Grains
LC-MS/MS
Uptake
Albero Romano, María Beatriz
Tadeo Lluch, José Luis
Miguel Gómez, María Esther
Pérez Martín, Rosa Ana
Rapid determination of antibiotic residues in cereals by liquid chromatography triple mass spectrometry
description 11 Pág.
author2 Ministerio de Economía, Industria y Competitividad (España)
author_facet Ministerio de Economía, Industria y Competitividad (España)
Albero Romano, María Beatriz
Tadeo Lluch, José Luis
Miguel Gómez, María Esther
Pérez Martín, Rosa Ana
format artículo
topic_facet Analysis
Antibiotics
Grains
LC-MS/MS
Uptake
author Albero Romano, María Beatriz
Tadeo Lluch, José Luis
Miguel Gómez, María Esther
Pérez Martín, Rosa Ana
author_sort Albero Romano, María Beatriz
title Rapid determination of antibiotic residues in cereals by liquid chromatography triple mass spectrometry
title_short Rapid determination of antibiotic residues in cereals by liquid chromatography triple mass spectrometry
title_full Rapid determination of antibiotic residues in cereals by liquid chromatography triple mass spectrometry
title_fullStr Rapid determination of antibiotic residues in cereals by liquid chromatography triple mass spectrometry
title_full_unstemmed Rapid determination of antibiotic residues in cereals by liquid chromatography triple mass spectrometry
title_sort rapid determination of antibiotic residues in cereals by liquid chromatography triple mass spectrometry
publisher Springer
publishDate 2019-09-01
url http://hdl.handle.net/10261/341355
http://dx.doi.org/10.13039/501100010198
https://api.elsevier.com/content/abstract/scopus_id/85068847210
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