Combination of Δ47 and U-Pb dating in tectonic calcite veins unravel the last pulses related to the Pyrenean Shortening (Spain)

Clumped isotopes thermometry (Δ47) and U-Pb dating of carbonates have been used to elucidate the temperature-time conditions of 10 tectonic calcite veins in the hanging wall of the South Pyrenean Frontal Thrust (Spain), the youngest thrust unit in the south-central Pyrenees. The Δ47 values indicate precipitation temperatures below ∼90 °C, in agreement with fluid inclusion analyses. 6 veins have been successfully dated, giving ages between 61 and 14.5 Ma with all but one value below 24 Ma. On the basis of our new results, we propose that several the studied veins record the end of Pyrenean tectonics in the area during the Burdigalian, possibly up to the Serravalian, younger than estimates based on magnetostratigraphic data from continental syn-tectonic deposits. Calculated δ18O values of the precipitating fluid are either very positive, suggesting a local source that has interacted with the host rock, or negative, suggesting the downward incursion of meteoric waters. For undated or pre-burial veins, the Δ47 values derived from temperature history reordering model (THRM) show that the measured Δ47 values may have been significantly altered during burial, preventing their use as a reliable thermal or paleohydrological marker. Although applied to a limited number of samples, these results highlight the great potential of the U-Pb/Δ47 approach to decipher the history of vein or cement formation and fluid flow in complex tectonic zones, provided that (i) the thermal evolution is known and (ii) the extent of clumped isotope reordering is systematically modelled.

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Main Authors: Hoareau, Guilhem, Crognier, Nemo, Lacroix, Brice, Aubourg, Charles, Roberts, Nick M.W., Niemi, Nathan, Branellec, Mathieu, Beaudoin, Nicolas, Suárez Ruiz, Isabel
Other Authors: Ministère de la Recherche et des Technologies (France)
Format: artículo biblioteca
Language:English
Published: Elsevier 2020-10-19
Subjects:clumped isotopes, carbonate U-Pb geochronology, veins, fractures, Pyrenees,
Online Access:http://hdl.handle.net/10261/266104
https://api.elsevier.com/content/abstract/scopus_id/85092915924
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spelling dig-incar-es-10261-2661042024-05-19T20:48:45Z Combination of Δ47 and U-Pb dating in tectonic calcite veins unravel the last pulses related to the Pyrenean Shortening (Spain) Hoareau, Guilhem Crognier, Nemo Lacroix, Brice Aubourg, Charles Roberts, Nick M.W. Niemi, Nathan Branellec, Mathieu Beaudoin, Nicolas Suárez Ruiz, Isabel Ministère de la Recherche et des Technologies (France) Suárez Ruiz, Isabel [0000-0003-4941-2797] clumped isotopes carbonate U-Pb geochronology veins fractures Pyrenees Clumped isotopes thermometry (Δ47) and U-Pb dating of carbonates have been used to elucidate the temperature-time conditions of 10 tectonic calcite veins in the hanging wall of the South Pyrenean Frontal Thrust (Spain), the youngest thrust unit in the south-central Pyrenees. The Δ47 values indicate precipitation temperatures below ∼90 °C, in agreement with fluid inclusion analyses. 6 veins have been successfully dated, giving ages between 61 and 14.5 Ma with all but one value below 24 Ma. On the basis of our new results, we propose that several the studied veins record the end of Pyrenean tectonics in the area during the Burdigalian, possibly up to the Serravalian, younger than estimates based on magnetostratigraphic data from continental syn-tectonic deposits. Calculated δ18O values of the precipitating fluid are either very positive, suggesting a local source that has interacted with the host rock, or negative, suggesting the downward incursion of meteoric waters. For undated or pre-burial veins, the Δ47 values derived from temperature history reordering model (THRM) show that the measured Δ47 values may have been significantly altered during burial, preventing their use as a reliable thermal or paleohydrological marker. Although applied to a limited number of samples, these results highlight the great potential of the U-Pb/Δ47 approach to decipher the history of vein or cement formation and fluid flow in complex tectonic zones, provided that (i) the thermal evolution is known and (ii) the extent of clumped isotope reordering is systematically modelled. This work benefited from a PhD grant of the French Ministry of Research (MESR) to NC. All analyses and field work performed in the course of this study were funded by a “CNRS excellence chair” grant to GH. Peer reviewed 2022-04-04T09:12:31Z 2022-04-04T09:12:31Z 2020-10-19 artículo http://purl.org/coar/resource_type/c_6501 Earth and Planetary Science Letters 553: 116636 (2021) 0012-821X http://hdl.handle.net/10261/266104 10.1016/j.epsl.2020.116636 2-s2.0-85092915924 https://api.elsevier.com/content/abstract/scopus_id/85092915924 en Earth and Planetary Science Letters https://doi.org/10.1016/j.epsl.2020.116636 Sí none Elsevier
institution INCAR ES
collection DSpace
country España
countrycode ES
component Bibliográfico
access En linea
databasecode dig-incar-es
tag biblioteca
region Europa del Sur
libraryname Biblioteca del INCAR España
language English
topic clumped isotopes
carbonate U-Pb geochronology
veins
fractures
Pyrenees
clumped isotopes
carbonate U-Pb geochronology
veins
fractures
Pyrenees
spellingShingle clumped isotopes
carbonate U-Pb geochronology
veins
fractures
Pyrenees
clumped isotopes
carbonate U-Pb geochronology
veins
fractures
Pyrenees
Hoareau, Guilhem
Crognier, Nemo
Lacroix, Brice
Aubourg, Charles
Roberts, Nick M.W.
Niemi, Nathan
Branellec, Mathieu
Beaudoin, Nicolas
Suárez Ruiz, Isabel
Combination of Δ47 and U-Pb dating in tectonic calcite veins unravel the last pulses related to the Pyrenean Shortening (Spain)
description Clumped isotopes thermometry (Δ47) and U-Pb dating of carbonates have been used to elucidate the temperature-time conditions of 10 tectonic calcite veins in the hanging wall of the South Pyrenean Frontal Thrust (Spain), the youngest thrust unit in the south-central Pyrenees. The Δ47 values indicate precipitation temperatures below ∼90 °C, in agreement with fluid inclusion analyses. 6 veins have been successfully dated, giving ages between 61 and 14.5 Ma with all but one value below 24 Ma. On the basis of our new results, we propose that several the studied veins record the end of Pyrenean tectonics in the area during the Burdigalian, possibly up to the Serravalian, younger than estimates based on magnetostratigraphic data from continental syn-tectonic deposits. Calculated δ18O values of the precipitating fluid are either very positive, suggesting a local source that has interacted with the host rock, or negative, suggesting the downward incursion of meteoric waters. For undated or pre-burial veins, the Δ47 values derived from temperature history reordering model (THRM) show that the measured Δ47 values may have been significantly altered during burial, preventing their use as a reliable thermal or paleohydrological marker. Although applied to a limited number of samples, these results highlight the great potential of the U-Pb/Δ47 approach to decipher the history of vein or cement formation and fluid flow in complex tectonic zones, provided that (i) the thermal evolution is known and (ii) the extent of clumped isotope reordering is systematically modelled.
author2 Ministère de la Recherche et des Technologies (France)
author_facet Ministère de la Recherche et des Technologies (France)
Hoareau, Guilhem
Crognier, Nemo
Lacroix, Brice
Aubourg, Charles
Roberts, Nick M.W.
Niemi, Nathan
Branellec, Mathieu
Beaudoin, Nicolas
Suárez Ruiz, Isabel
format artículo
topic_facet clumped isotopes
carbonate U-Pb geochronology
veins
fractures
Pyrenees
author Hoareau, Guilhem
Crognier, Nemo
Lacroix, Brice
Aubourg, Charles
Roberts, Nick M.W.
Niemi, Nathan
Branellec, Mathieu
Beaudoin, Nicolas
Suárez Ruiz, Isabel
author_sort Hoareau, Guilhem
title Combination of Δ47 and U-Pb dating in tectonic calcite veins unravel the last pulses related to the Pyrenean Shortening (Spain)
title_short Combination of Δ47 and U-Pb dating in tectonic calcite veins unravel the last pulses related to the Pyrenean Shortening (Spain)
title_full Combination of Δ47 and U-Pb dating in tectonic calcite veins unravel the last pulses related to the Pyrenean Shortening (Spain)
title_fullStr Combination of Δ47 and U-Pb dating in tectonic calcite veins unravel the last pulses related to the Pyrenean Shortening (Spain)
title_full_unstemmed Combination of Δ47 and U-Pb dating in tectonic calcite veins unravel the last pulses related to the Pyrenean Shortening (Spain)
title_sort combination of δ47 and u-pb dating in tectonic calcite veins unravel the last pulses related to the pyrenean shortening (spain)
publisher Elsevier
publishDate 2020-10-19
url http://hdl.handle.net/10261/266104
https://api.elsevier.com/content/abstract/scopus_id/85092915924
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