Some problems on the silicate analysis method for sea water.
The molybdenum yellow method (Robinson, R. J. and T. G. Thompson, 1948 and Oceanographical Society of Japan, 1963) has been generally applied for silicate analysis of sea water in the serial oceanographic observations in Japan. However, it seems this method has some problems to be solved concerning reagent concentrations and standard solutions. This report is an experimental study on the molybdenum yellow method for the analysis of reactive silicate in sea water. Optical characteristics of the photoelectric colorimeter for silicate analysis and effects of reagent concentration, temperature and salts in sample solution on color development of molybdenum yellow were examined and also difference of absorbancy between sodium silicate standard solution and potassium chromate solution was checked. From these experimental results, it is concluded that some correction must be added as soon as possible to silicate data obtained by a photoelectric colorimeter which was calibrated with potassium chromate solution as the standard.
Main Author: | |
---|---|
Format: | Journal Contribution biblioteca |
Language: | Japanese |
Published: |
1968
|
Online Access: | http://hdl.handle.net/1834/16388 |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
id |
dig-aquadocs-1834-16388 |
---|---|
record_format |
koha |
spelling |
dig-aquadocs-1834-163882021-05-19T06:56:15Z Some problems on the silicate analysis method for sea water. Higano, Ryoji The molybdenum yellow method (Robinson, R. J. and T. G. Thompson, 1948 and Oceanographical Society of Japan, 1963) has been generally applied for silicate analysis of sea water in the serial oceanographic observations in Japan. However, it seems this method has some problems to be solved concerning reagent concentrations and standard solutions. This report is an experimental study on the molybdenum yellow method for the analysis of reactive silicate in sea water. Optical characteristics of the photoelectric colorimeter for silicate analysis and effects of reagent concentration, temperature and salts in sample solution on color development of molybdenum yellow were examined and also difference of absorbancy between sodium silicate standard solution and potassium chromate solution was checked. From these experimental results, it is concluded that some correction must be added as soon as possible to silicate data obtained by a photoelectric colorimeter which was calibrated with potassium chromate solution as the standard. Published 2020-02-19T17:16:51Z 2020-02-19T17:16:51Z 1968 Journal Contribution Refereed http://hdl.handle.net/1834/16388 ja https://www1.kaiho.mlit.go.jp/GIJUTSUKOKUSAI/KENKYU/report/rhr04/rhr04-03.pdf pp.21-27 |
institution |
UNESCO |
collection |
DSpace |
country |
Francia |
countrycode |
FR |
component |
Bibliográfico |
access |
En linea |
databasecode |
dig-aquadocs |
tag |
biblioteca |
region |
Europa del Oeste |
libraryname |
Repositorio AQUADOCS |
language |
Japanese |
description |
The molybdenum yellow method (Robinson, R. J. and T. G. Thompson, 1948 and Oceanographical Society of Japan, 1963) has been generally applied for silicate analysis of sea water in the serial oceanographic observations in Japan. However, it seems this method has some problems to be solved concerning reagent concentrations and standard solutions.
This report is an experimental study on the molybdenum yellow method for the analysis of reactive silicate in sea water.
Optical characteristics of the photoelectric colorimeter for silicate analysis and effects of reagent concentration, temperature and salts in sample solution on color development of molybdenum yellow were examined and also difference of absorbancy between sodium silicate standard solution and potassium chromate solution was checked.
From these experimental results, it is concluded that some correction must be added as soon as possible to silicate data obtained by a photoelectric colorimeter which was calibrated with potassium chromate solution as the standard. |
format |
Journal Contribution |
author |
Higano, Ryoji |
spellingShingle |
Higano, Ryoji Some problems on the silicate analysis method for sea water. |
author_facet |
Higano, Ryoji |
author_sort |
Higano, Ryoji |
title |
Some problems on the silicate analysis method for sea water. |
title_short |
Some problems on the silicate analysis method for sea water. |
title_full |
Some problems on the silicate analysis method for sea water. |
title_fullStr |
Some problems on the silicate analysis method for sea water. |
title_full_unstemmed |
Some problems on the silicate analysis method for sea water. |
title_sort |
some problems on the silicate analysis method for sea water. |
publishDate |
1968 |
url |
http://hdl.handle.net/1834/16388 |
work_keys_str_mv |
AT higanoryoji someproblemsonthesilicateanalysismethodforseawater |
_version_ |
1756076729586155520 |